Optically induced effects in thin films of indandione type organic 在2型有机薄膜光诱导的影响.pptVIP

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Optically induced effects in thin films of indandione type organic 在2型有机薄膜光诱导的影响.ppt

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Optically induced effects in thin films of indandione type organic 在2型有机薄膜光诱导的影响

Optically induced effects in thin films of indandione type organic molecules Inta Muzikante Institute of Solid State Physics, University of Latvia Valdis Kampars, Pauls Pastors Department of Chemistry, Riga Technical University Burkhard Stiller, Knut Moravetz, Dieter Neher Institute of Physics, Potsdam University Absorption spectra of DMABI derivativesin s-PMMA Modification of SHG effect by light SNOM images of gratings Diffraction experiment by visible light Absorption spectra of DMABI derivativesin s-PMMA * * COST ACTION P8 ?MATERIALS AND SYSTEMS FOR OPTICAL DATA STORAGE AND PROCESSING May 26-27, 2006, Loutraki. Greece 3 types of optical induced motions Photoisomerization of PDR1molecule on irradiation Institute of Solid State Physics, University of Latvia DR1 Disperse red Trans-isomer Cis-isomer Trans-isomer λ1 λ2 Photoinduced Intramolecular Electron Transfer - PIET λPIET λPIET M.Rutkis, A.Vembris, V.Zauls, A.Tokmakovs, E.Fonavs,A.Jurgis, V.Kampars, Proc.SPIE, 2006, 6192, 6192Q, Twisting of DMABI molecule on irradiation in PIET Institute of Solid State Physics, University of Latvia Indandione type molecules DMABI DD-DMABI Institute of Solid State Physics, University of Latvia Samples – host-guest films The chromophore - syndioatactic poly methyl methacrylate (sPMMA) (molecular mass 260000) host- guest films within the concentration of 9 wt% has been investigated. Films were prepared by casting from chloroform solutions on glass slides as substrates. To evacuate chloroform, samples were vacuum dried at room conditions (~25 oC) for 3 days. Film thickness were between 4 and 5.5 μm Institute of Solid State Physics, University of Latvia Institute of Solid State Physics, University of Latvia Photoinduced reversible changes of surface potential Institute of Solid State Physics, University of Latvia 1 wt% DMABI/iPMMA Corona oriented sample 10 wt% DMABI/sPMMA Wavelength 1064 nm Beam diameter ~ 0.1 mm Write average power ~ 50 W/cm2 Read average power ~ 0.5 W