义务教育14-2.pptVIP

Like cyclohexane rings (Section 2.9), pyranose rings have a chair-like geometry with axial and equatorial substituents. By convention, the rings are usually drawn by placing the hemiacetal oxygen atom at the right rear. Note that an -OH group on the right in a Fischer projection is on the bottom face of the pyranose ring, and an -OH group on the left in a Fischer projection is on the top face of the ring. Both anomers of D-glucopyranose can be crystallized and purified. Pure α-D-glucopyranose has a melting point of 146℃ and a specific rotation [α]D = +112.2°; pure β -D-glucopyranose has a