磷酸铁锂动力电池的高低温性能解决途径.ppt

Introduction Cathode: particle size minimization or doping 1.0m(0.9LiBF4–0.1LiBOB) 1:1:3 PC/EC/EMC electrolyte LiFePO4/C高温性能研究 Electrolyte Design 1.0m(0.9LiBF4–0.1LiBOB) 1:1:3 PC/EC/EMC electrolyte Anode coating LiFe(PO4)1-xFx/C cathode F 取代对LiFePO4结构的影响 Summary 973 Program of China (2007CB209705) Natural Science Foundation of China Natural Science Foundation of Shanghai (07JC14024). Shanghai Jiao Tong University * Approaches to improve the electrochemical performance of LiFePO4-based lithium ion batteries working in a wide temperature range Zi-Feng Ma Department of Chemical Engineering Shanghai Jiao Tong University, Shanghai 200240, China E-mail: zfma@sjtu.edu.cn 磷酸铁锂动力电池的高低温性能解决途径 前期工作基础： 上海交通大学在LiFePO4正极材料制备新工艺方面，获得6项中国发明专利(专利号: ZL 200410018476.4等) ；2004年开始与浙江横店东磁股份有限公司合作开展产业化技术开发，获得2006年浙江省产业化转化项目，2008年初完成中试线。 Mechanical chemical reaction Fe+2FePO4+Li3PO4.0.5H2O →3LiFePO4 + 0.5H2O Xiao-Zhen Liao, Zi-Feng Ma*, Liang Wang, Xiao-Ming Zhang, Yi Jiang, Yu-Shi He, Electrochem. Solid-State Lett. 2004, 7(12)：A522-525 （SCI Cited 33) Xiao-Zhen Liao, Zi-Feng Ma*, Yu-Shi He, Xiao-Ming Zhang, Liang Wang, Journal of the Electrochemical Society, 2005, 152(10):A1969-1972 (SCI cited 25) 2008年全国优秀博士学位论文提名奖；2007年上海市优秀博士学位论文 现有生产能力：年产150吨磷酸铁锂正极材料 近期目标：合资建立磷酸铁锂动力电池生产线 36V12Ah Introduction In winter, the electric vehicle have to be started at low temperature and the battery need to keep better performance Introduction Approaches to enhance the performance of LiFePO4/C cathode at low temperature Electrolyte: Solvent selection: affects liquid temperature range and viscosity, and participating in the formation of a solid electrolyte interface (SEI), the resistance of which is main resistance in the full cell.(两元、三元或四元） Lithium salt: LiPF6, LiBF4, LiBOB et al K. Amine, J. Liu, I. Belharouak, Electrochem. Commun. 7 (2005) 669. Effect of salt ratio on the discharge voltage of Li/LiFePO4 cells, which was measured at 1C by charging the cell at 20 ?C and then dischargin