Zn与Zn15Al喷涂层在草甸土与盐碱土模拟液中的腐蚀行为.doc

Electrochemical Corrosion Behavior of Arc Sprayed Zn and Zn15Al Coatings in Simulated Salina Soil and Neutral Meadow Soil Solutions LIN Bi-lan1, LU Xin-ying1, LI Long2 (1. Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China; 2. Guangdong Sanhe Pipe-pile Co. Ltd., Zhongshan 518424, China) Abstract: Arc sprayed Zn and Zn15Al coatings were chosen to protect the metal ends of Prestressed High-strength Concrete (PHC) pipe piles against corrosion of salina soil in Northern China and neutral meadow soil in Northeast China. The corrosion behavior of the coated Q235 steel samples in two simulated soil solutions were investigated by potentiodynamic polarization and Electrochemical Impedance Spectroscopy (EIS) methods. The results show that the corrosion of the matrix Q235 steel in both simulated solutions is remarkably inhibited by Zn and Zn15Al coatings. The corrosion products on Zn and Zn15Al are thick, compact, firm and protective. The corrosion current density icorr of both Zn and Zn15Al coated samples is decreased evidently with testing time, and the charge transfer resistance Rct is increased remarkably. The corrosion resistance indexes of Zn and Zn15Al in simulated neutral meadow soil solution are more predominant than those in salina soil. The corrosion resistance of Zn15Al in salina soil is a little superior to that of Zn. When the sprayed coatings were sealed with epoxy resin, the corrosion resistance of the coatings is enhanced evidently. Keywords: arc spray; coatings; soil; corrosion; EIS; electrochemical 1 Introduction PHC pipe piles are increasingly to be used in some aggressive areas of Northern and Northeast China, which have been originated and widely used in Southern China. With the demanding durability requirements about the engineering structures [1,2], the durability of PHC pipe piles should be clarified as the anticorrosion behaviors of the pile body and the metal ends. The durability of the concrete pile body has been investigated