改性豆渣吸附重金属Pb2+性能研究.docxVIP

毕业设计（论文）题目改性豆渣吸附重金属Pb2+的性能研究系（院）化学工程系专业化学工程与工艺班级2010级本一班学生姓名学号指导教师职称二〇一四年六月二十三日改性豆渣吸附重金属Pb2+的性能研究摘要本研究以豆渣（BD）为原料，研究了用NaOH（NBD）、乙二胺（EBD）、环氧氯丙烷（CBD）等不同试剂改性豆渣作为吸附剂，吸附废水中的重金属离子Pb2+。研究了溶液初始浓度、吸附温度、溶液pH、吸附时间对改性豆渣吸附剂吸附废水中重金属离子Pb2+吸附性能的影响。由此得出了改性豆渣吸附剂的最佳吸附条件。并对改性豆渣吸附剂吸附Pb2+进行一级动力学与二级动力学拟合，拟合结果表明该吸附过程更符合二级动力学模型。吸附过程为物理吸附。改性豆渣吸附剂吸附Pb2+等温线更符合Freundlich方程。吸附过程为多层吸附。热力学参数显示，改性豆渣吸附Pb2+的过程，是吸热的，自发的过程。通过对改性豆渣吸附剂与未改性豆渣（RBD）吸附剂吸附性能进行对比，得出改性豆渣吸附剂对Pb2+的吸附效果明显优于未改性豆渣吸附剂。关键词：改性豆渣、吸附、环氧氯丙烷、乙二胺、NaOHThe performance of the modified bean dregs heavy metal adsorption Pb2+ researchAbstractThree types of chemically modified soybean hulls were prepared by treating bean dregs（BD）with sodium hydroxide (NBD), ethylenediamine (EBD), and epoxy chloropropane (CBD)To study the adsorption temperature, initial concentration, solution pH, adsorption time on modified bean dregs Pb2+ ions adsorption of heavy metals in waste water absorbent adsorption performance influence.Conclusion: the modified bean dregs adsorbent optimum adsorption conditions.And the modified bean dregs adsorbent adsorption kinetics of Pb2+primary and secondary fitting, the fitting results show that the adsorption process conforms to the level 2 dynamic model.Adsorption process for physical adsorption.Modified bean dregs adsorbent adsorption isothermal Pb2+ in accordance with the Freundlich equation.Adsorption process for the single molecular adsorption. The thermodynamic parameters showed that Pb2+ sorption onto soybean hulls was an endothermic, positively entropic，and spontaneous sorption process.Through the modification of bean dregs adsorbent compared with unmodified bean dregs（RBD） adsorbent adsorption performance, it is concluded that modified bean dregs adsorbent for the adsorption of Pb2+ effect is obviously better than that of the unmodified solids adsorbent.Keywords: modified bean dregs, adsorption, epoxy chloropropane, ethylenediamine, NaOH目录引言错误！未定义书签。第一章绪论错误！未定义书签。1.1水体中的重金属污染错误！未定义书签。1.1.1水体中重金属的危害错误！未定义书签。1.1.2废水中重金属去除的研究现