不同表面状态钢筋在含氯混凝土中腐蚀行为分析-analysis of corrosion behavior of steel bars with different surface states in chlorine-containing concrete.docxVIP

cooled had a lot of defects. The oxide scale with air-cooled exhibited more excellent corrosion resistance compared with that oxide scale with water-cooled.The corrosion behaviors of steel with different surface states in concrete containing chloride were studied by electrochemical methods. When the steel was start to corrode, the chloride threshold level (CTL) through taking and analyzing chloride ions content around the steel was obtained. The results indicated that both steels were protected by the passive film in the concrete containing chloride. When critical chloride content reaches the steel surface, the passive film was broken, the steel with nude surface needs 30 days. The steel with water-cooled and air-cooled oxide scale need 60 days and 70 days. Compared with the steel with nude surface, the steel with oxide scale had higher CTL. The CTL of the steel with nude surface, water-cooled and air-cooled oxide scale were 0.305%, 0.488% and 0.527%. The steel with oxide scale showed better corrosion resistance in concrete containing chloride. The steel with water-cooled oxide scale cannot compete in corrosion resistance with the steel with air-cooled oxide scale.Key Words ： Steel reinforced concrete ； Chloride ； Oxide scale ； Corrosion ；ElectrochemicalIII目录摘要 IAbstract II引言 - 1 -1 文献综述 - 2 -1.1 混凝土中钢筋腐蚀的研究现状 - 2 -1.1.1 钢筋腐蚀对混凝土耐久性影响 - 2 -1.1.2 混凝土中钢筋腐蚀的机理 - 4 -1.2 混凝土内钢筋腐蚀的检测方法 - 6 -1.2.1 物理法 - 6 -1.2.2 半电池电位法 - 7 -1.2.3 线性极化法 - 9 -1.2.4 弱极化曲线法 - 10 -1.2.5 交流阻抗法 - 12 -1.3 氯离子引起的钢筋腐蚀 - 13 -1.3.1 氯离子造成钢筋腐蚀的机理 - 13 -1.3.2 临界氯离子浓度的研究现状 - 14 -1.4 不同表面状态钢筋的腐蚀行为研究现状 - 16 -1.5 本文主要研究内容 - 17 -2 Q235 钢筋混凝土在不同浓度 NaCl 水溶液中的腐蚀行为 - 19 -2.1 前言 - 19 -2.2 实验材料 - 19 -2.3 实验方法 - 19 -2.3.1 试样制备 - 19 -2.3.2 电化学测试 - 20 -2.4 实验结果 - 21 -2.4.1 自腐蚀电位 - 21 -2.4.2 电化学阻抗谱的测定 - 22 -2.4.3 弱极化曲线的测定 - 25 -2.5 分析与讨论 - 27 -2.6 本章小结 - 29 -3 不同表面状态的 Q235 钢在 3.5% NaCl 水溶液中的腐蚀行为 - 30 -3.1 前言 - 30 -3.2 实验方法 - 30 -3.2.1 试样制备 - 30 -3.2.2 氧化皮表