氢氧化铍中硫酸根的去除试验的研究.docVIP

南华大学核资源工程学院毕业设计第 第 1页 共 NUMPAGES \* MERGEFORMAT 21 页 毕业设计(论文)题 目 Be(OH)2中SO42-的去除试验研究 学院名称 核资源工程学院 指导教师 职 称 教 授 班 级 1 学 号 学生姓名 Be(OH)2中SO42-的去除试验研究摘要：随着国家对核电事业的大力投资建设，氟化铍作为新型第四代核反应堆堆芯的传热材料，对其纯度要求非常高。而氢氧化铍是制取氟化铍的重要原料，研究去除氢氧化铍中的硫酸根并达到要求的纯度，有很重要的研究意义和研究价值。某铍矿生产企业生产的Be(OH)2中SO42-含量为5.17%左右，根据核纯级Be(OH)2的要求，要求Be(OH)2中SO42-含量达到0.05%以下。根据Be(OH)2的性质，结合去除低浓度SO42-的方法，分别用洗涤法、氯化钡沉淀法、片碱溶解再沉淀法进行去除硫酸根的实验研究，得出相关结论。实验结果表明：洗涤法处理后的Be(OH)2试样含SO42-约3%，达不到工艺要求；氯化钡沉淀法去除SO42-后，得到的Be(OH)2含SO42-约0.05%左右，基本达到工艺要求；先用片碱溶解Be(OH)2后，再用盐酸使Be(OH)2析出，得到的Be(OH)2含SO42-达到0.2%，去除效果不好。此次实验中，氯化钡沉淀法去除硫酸根效果最好。关键词：去除低浓度SO42-，洗涤法，氯化钡沉淀法，氢氧化钠溶解再沉淀法Experimental study on removal of sulfate in beryllium hydroxideAbstract: Along with the national investment construction of the nuclear power industry, heat transfer material beryllium fluoride as the new fourth generation nuclear reactor core, the very high purity requirements. Hydrogen is an important raw material for producing beryllium oxide beryllium fluoride, removal of sulfate beryllium hydroxide in to achieve the required purity, valuable research significance and the research is very important. The sulfate content of beryllium hydroxide production of a beryllium ore production of about 5.17%, according to the nuclear grade beryllium hydroxide requirements, requirements of sulfate content beryllium hydroxide to below 0.05%. According to the properties of beryllium hydroxide, combined with the method of removing low concentration of sulfate, experiments were conducted to study the removal of sulfate were used to washing method, barium chloride precipitation, alkali dissolution reprecipitation method, draw relevant conclusions.The experimental results show that: beryllium hydroxide sample washing after processing sulfate-containing about 3%, not up to process req