利用乙炔炭黑薄膜修饰电极α萘乙酸电化学检测.docVIP

湖北民族学院学士学位论文PAGE PAGE 1目 录摘要1、中文摘要··························································22、英文摘要·························································3一、前言···································································41、α-萘乙酸························································42、玻碳电极···························································43、薄膜修饰电极····················································54、乙炔炭黑和双十六烷基磷酸····································55、电极反应过程····················································66、研究目的·························································7二、实验部分·····························································71、试剂·······························································72、实验仪器··························································73、乙炔炭黑薄膜修饰电极的制备······································74、分析步骤··························································8三、结果与讨论··························································81、AB / DHP薄膜修饰GCE的电化学的行为····························82、NAA的电化学行为··················································93、扫描频率的影响····················································104、AB／DHP悬浮液的量的影响·········································105、富积时间的影响····················································116、可重复性和再生性···············································117、线性范围和检测极限············································128、干扰试验·························································129、分析应用·························································13四、结论·································································13五、参考文献····························································13六、致 谢································································15利用乙炔炭黑薄膜修饰电极的α-萘乙酸电化学检测 中文摘要：通过超声波振荡，将乙炔碳黑（AB）分散在双十六烷基磷酸溶液（DHP）中,形成稳定的分散均匀的AB/DHP悬浮液。蒸发掉水分之后，即得到AB/DHP混合薄膜修饰电极。以裸电极时对K3[Fe( CN)6]的响应为基准，观测DHP修饰电极与AB/DHP薄膜修饰电极。结果发现AB/DHP薄膜修饰电极有大的表面积，以及具有电子迁移速率恒定不变的特性，此外，检测α-萘乙酸（NAA）在电极上的电化学行为，发现在AB/DHP薄膜修饰电极上α-萘乙酸（NAA）氧化峰