FCC汽油生产IV标准清洁汽油.pptVIP

To enlarge the pore size of SAPO-11 in the composite, we developed a novel alcohol-thermal method to synthesize SAPO-11 instead of the conventional hydrothermal synthesis. By adjusting the alcohol-water ratio, we can control the hydrolysis degree of TEOS. By this way, TEOS is incorporated into the zolite framework with different numbers of organic groups and thus the average pore diameter of the resulting SAPO-11 can be tuned from 0.6 nm to 0.8-1.0 nm. * * * After modification with the above two methods, the composite derived catalyst show interesting upgrading performance. It decreases the olefin content of FCC gasoline by 18 v% and the gasoline yield is as high as 98%. Moreover, these results are achieved with only small loss in gasoline research octane number. However, The desulfurization ratio is not so high, with the sulfur content of the upgraded gasoline being as high as regulated by China IV. So, the question how to further decrease sulfur content of FCC gasoline arises. As we know, olefin saturation and hydrodesulfurization reactions take place on metal sulfide particles supported on alumina. The rim sites are active for both hydrogenation of olefins and hydrodesulfurization of sulfur-containing compounds, while edge sites are only active for HDS. Obviously, the route to achieve highly selective HDS is to maximizing the ratio of edge sites. Increasing the stacking of metal sulfide is good for selectivity, but gives rise to lower activity; increasing the dispersion of metal sulfide gives high activity, but results in lower selectivity. This suggests that to achieve both higher desulfurization ratio and higher selectivity, there must be a compromise between dispersion and stacking of metal sulfide. * * * The resulting catalyst shows very good selective HDS performance for both full range FCC gasoline and heavier fraction after cutting, giving a HDS ratio of 77-80% for full range FCC gasoline and a HDS ratio of 82-87% for heavier fraction, while the olefin