ag替位取代cu2znsns4光伏材料的探究起色.pdfVIP

Journal of Advances in Physical Chemistry 物理化学进展, 2018, 7(2), 55-63 Published Online May 2018 in Hans. /journal/japc /10.12677/japc.2018.72007 Progress on Ag Substitution in Cu ZnSnS 2 4 Photovoltaic Materials 1 1 1 2 1* Junqiang Hu , Cunpeng Qin , Shuhong Sun , Yongmao Hu , Yan Zhu 1 Kunming University of Science and Technology, Kunming Yunnan 2 Dali University, Dali Yunnan th th th Received: Mar. 10 , 2018; accepted: May 7 , 2018; published: May 14 , 2018 Abstract Cu ZnSnS (CZTS) is an attractive p-type semiconductor material. However, the power conversion 2 4 efficiency of CZTS is limited by the losses of the open circuit voltage, which is resulted by a large number of CuZn and ZnCu antisite defects. Researchers have tried many methods to reduce this loss and improve the power conversion efficiency. Among them, the replacement of Cu sites in CZTS with Ag ions is a more effective approach. This article summarizes the recent research progress on (Cu Ag ) ZnSnS (CAZTS) and Ag ZnSnS (AZTS) (x = 1). 1-x x 2 4 2 4 Keywords (Cu Ag ) ZnSnS , Substitution, CZTS 1-x x 2 4 Ag替位取代Cu ZnSnS 光伏材料的研究进展 2 4 1 1 1 2 1* 胡俊强 ，秦存鹏，孙淑红，胡永茂，朱 艳 1 昆明理工大学，云南 昆明 2大理大学，云南 大理 收稿日期：2018年3月10 日；录用日期：2018年5月7 日；发布日期：2018年5月14 日 摘 要 Cu ZnSnS (CZTS)是一种非常有前景的p型半导体材料。然而，其光电转换效率受到大量Cu