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國立宜蘭大學環境工程學系(所)碩士論文初稿Department of Environmental EngineeringNational Ilan UniversityMaster Thesis Draft利用廢石英砂製備中孔洞與微孔材料進行高溫下二氧化碳處理之研究Study on the Treatment of Carbon dioxide under High Temperature by Mesoporous and Microporous Materials Made from Spent Quartz Sand指導教授：張章堂博士Chang, Chang-Tang, Ph D研究生: 蘇毅騰研究生: Yiteng Su中華民國一百零三年三月Error摘要近年來，隨著工業的快速成長以及各項產業的崛起，使民眾的生活便利許多，但也間接的導致各種汙染物的產生。其中，二氧化碳作為溫室氣體對地球暖化造成了諾大的影響，隨著交通工具的普及，二氧化碳的排放亦日漸增加，如何減緩二氧化碳上升趨勢成為現下重要的研究議題之一。本文使用溴化銨(cetyltrimethyl CTAB)為陽離子型表面活性劑和石英砂作為矽源合成微/介孔材料。後使用3-氨基丙基三甲氧基矽烷(3-aminopropyltrimethoxysilane APTS), 乙二胺(ethylenediamine EDA)與單乙醇胺(monoethanolamine MEA)改質合成之微/介孔材料。微/介孔材料吸附材料經x射線螢光光譜儀(XRF)、氮氣等溫吸附/脫附儀、元素分析儀(EA)、掃描電子顯微鏡(SEM),傅立葉紅外光譜(FTIR)、熱重分析儀(TGA) 、X射线粉末衍射(XRD)和二氧化碳分析儀分析。本研究利用廢石英砂合成Q-MCM材料，後再使用APTS改質Q-MCM材料負載上氨基得A-Q-MCM,在室溫條件下比未改質材料有更好的二氧化碳吸附能力；而使用EDA與MEA改質Zeolite-Y材料，得到之Zeo-EDA-X%與Zeo-MEA-X%在二氧化碳吸附能力上也有顯著提升。AbstractWith the rapidly developing of manufacture and more and more industries rise sharply in recent years. It makes the live of people become convenient. But it also introduce some pollutant into the environment. Carbon dioxide as one of the green house gas it makes great influence on the global warming. with vehicle popularly the emission of carbon dioxide increasing which makes the mitigation of GHS become one of the most important issues.Mesoporous MCM-41 was synthesized using cetyltrimethyl ammonium bromide (CTAB) as a cationic surfactant and spent quartz sand as the silica source. Modification of the mesoporous structure to create an absorbent was then completed using 3-aminopropyltrimethoxysilane.The A-Q-MCM adsorbents were then characterized by N2 adsorption/desorption, elemental analysis(EA), X-Ray Fluorescence (XRF), a scanning electron microscope(SEM), Fourier Transform infrared spectroscopy (FTIR) as well as the CO2 adsorption/ desorption performance. In this study spent quartz sand was utilized to synthesize Q-MCM and the amine functionalized material, A-Q-MCM, which exhibited a higher