Allosteric Cofacial Porphyrin Complexes超分子变构cofacial卟啉配合物ppt课件.pptVIP

Supramolecular Allosteric Cofacial Porphyrin Complexes;Allosteric Recognition;Introduction-Porphyrin;;Holliday, B. J. et. al. Angew. Chem. Int. Ed. 2001, 40, 2022-2043.;The Directional-Bonding Approach;The Symmetry-Interaction Approach;The Weak-Link Approach;Catalytic Acyl Transfer by a Cyclic Porphyrin Trimer;Design of Allosteric Porphyrin-Based Supramolecules;( i ) 1-bromo-2-chloroethane, K2CO3, Acetone, Reflux ( ii) 1,3-propanedithiol, Y(OTf)3 (5 mol %), CH3CN (iii) KPPh2, THF (iv) S8, THF ( v) NaNO2,AcCl/H2O, CH2Cl2, 0 °C → rt;( vi ) 5-mesityldipyrromethane, BF3?OEt2, DDQ, NEt3,