铌镱酸铅-钛酸铅陶瓷制备及机电性质分析-preparation and mechanical and electrical properties analysis of lead niobate - lead titanate ceramics.docxVIP

摘要PYN-0.495PT陶瓷的一套完整自洽的全矩阵机电参数。发现PYN-0.495PT陶瓷的压电性能明显好于工业常用的PZT-5A陶瓷，且由于具有低烧结温度和高居里点的特点，是一种可以替代PZT-5A的实用新型压电陶瓷材料。关键词：高居里温度,Pb(Yb1/2Nb1/2)O3–PbTiO3,热稳定性,机电性质,宏观畴-微观畴转变BAbstractLead-basedpiezoelectricceramicswithgoodperformancewaswidelyappliedanddeeplyresearched.Intheseapplications,piezoelectricdevicesusedindifferentenvironmentsrequirepiezoelectricceramicswithdifferentperformanceparameters,sonewrequirementsforpiezoelectricceramicsaredemanded:first,requirepiezoelectricceramicswithbothhighCurietemperatureandgoodpiezoelectricperformance.Second,duetotheleadevaporationandthepursuitoflowenergyconsumption,thereisanurgentneedtofindonekindofpiezoelectricceramicswithlowsinteringtemperature.Theexistingpiezoelectricceramicsaredifficulttomeettheaboverequirements,however,thenewbinaryPb(Yb1/2Nb1/2)O3-PbTiO3(PYN-PT)piezoelectricceramichashigherCurietemperature.Thepreparationconditionsincludingpresinteringtemperatureandsinteringtemperatureofthisbinarysystemhavebeenlittleresearched.Thecompletesetofelastic,dielectric,piezoelectricpropertiesofPYN-PTpiezoelectricceramicswhichisrequiredinthedesignprocessofthepiezoelectricdevicehasnotbeenreported.SoitisnecessarytoresearchthepreparationandtheelectromechanicalpropertiesofthePYN-PTpiezoelectricceramic.First,theimpactofpreparationconditionstotheperformanceofthePYN-PTpiezoelectricceramicwasdiscussed,thePYN-PTpiezoelectricceramicswithgoodperformancewereprepared.FoundthattheYbNbO4precursorhasformedagoodphasestructureat1200℃.ExploredthephasestructureandpiezoelectricpropertiesofthePYN-PTpiezoelectricceramicwithdifferentpresinteringtemperaturesandsinteringtemperatures,andfoundthatthemostsuitablepresinteringtemperatureandsinteringtemperatureare850℃and1000℃,respectively.Thenwesynthesizedfivecomponentswithxfrom0.49to0.51in(1-x)PYN-xPTsystem.Thephasestructure,TG-DSC,ferroelectrichysteresisloopandotherelectricalpropertiesofthisbinaryceramicnearMorphotropicPhaseBoundary(MPB)werestudied.ItwasfoundthatPYN-0.495PTceramicslocatedatMPBhavethelargestremanentpola