铌掺杂对na0.85k0.150.5bi0.5tio3薄膜力学和电学性能的影响-effect of nb doping on mechanical and electrical properties of na 0.85 k 0.150.5b i 0.5 tio 3 thin films.docxVIP

AbstractSincethevolatilityofleadinleadzirconatetitanate(PZT)causesenvironmentalpollution,peoplehavebeenlookingforlead-freeferroelectricmaterialstoreplacePZT.Sodiumbismuthtitanate(Na0.5Bi0.5TiO3,NBT)isanexcellentlead-freeferroelectricmaterials.ButNBThasthedefectsofhighcoercivefieldandlargeleakagecurrent,whichrestrictitsuse.Therefore,wewanttoimprovetheperformanceofNBTthinfilmbydoping.Firstly,A-sitepotassium-dopedNBTthinfilmswasstudiedandthemorphotropicphaseboundary(MPB)of(Na(1?x)Kx)0.5Bi0.5TiO3(NKBT100x)weredetermined.Then,B-siteniobium-dopedNKBT15thinfilmswerestudied.Themaincontentisshowedbelow:NKBT100x(x=0.11,0.13,0.15,0.17,0.19)thin?lmswerepreparedbymetal-organicdecomposition(MOD),andthephasestructures,surfacemorphologies,ferroelectricproperties,piezoelectricpropertiesanddielectricpropertiesathightemperatureoftheNKBT100xthinfilmshavebeenstudies.TheXRDresultsshowthatallthethin?lmsareofsingle-phaseperovskitestructureandthereisintimatecoexistenceoftwophasesinthepotassiumcontentrangex=0.13-0.17.TheMPBofNKBT100xthinfilmslocatedx=0.13-0.17,whichwasidenti?edbymulti-peak?ttingingrazingincidenceX-raydiffractionpatterns.TheNKBT17thin?lmisofthebestpiezoelectricproperties,whichisattributedtoahighdegreeofalignmentofferroelectricdomainsintheMPBregionanditslargestgrainsize.TheNKBT17thin?lmexhibitstheclassicaldiffusephasetransitionofarelaxorferroelectric,whichisdiscussedbycompositionalinhomogeneityandpolarnanoregions(PNRs).NKBT15-N100x(x=0,0.01,0.03,0.05,0.07)thinfilmswerealsopreparedbyMODmethod,andthephasestructures,surfacemorphologies,residualstressses,erroelectricproperties,piezoelectricpropertiesandleakagecurrentoftheNKBT15-N100xthinfilmshavebeensutdies.TheNKBT15-3Nthinfilmhasthebestcrystallinity,thesmallestelasticitymodulus(102.0Gpa),hardness(5.1Gpa),residualstress(297.0Mpa)andleakagecurrent,andthelargestremnantpolaritionandstatisticd33eff(140pm/V).Keywords:(Na0.85K0.15)0.5Bi0.5TiO3thinfilm;Nb-doping;morphotropicphaseboundary;mechanicalproperties;electricalproperties目录第1章绪论..