溶液剥离法制备几种二维纳米结构及其性能分析-preparation and properties analysis of several two-dimensional nanostructures by solution stripping method.docxVIP

II II 湘潭大学硕士毕业论文 湘潭大学硕士毕业论文 Abstract With the development of nanoscience and nanotechnology, two-dimensional (2D) nanostructures have attracted great attention owing to their unique microstructure, outstanding properties and potential use in broad fields. Furthermore, the emergences of some new systems about 2D nanostructures as well as the novel phenomenon and mechanisms appeared in these systems have also injected new vitality into the development of 2D nanomaterials. In the present thesis, we focused on the 2D nanostructures and systematically investigated the synthesis methods and performance characteristics of Bi2Te3 nanosheets, TiO2 nanosheets and graphene. The photoelectrochemical property of graphene-based nanocomposite is the major part of our investigation. This thesis includes six chapters. In Chapter one, there are the introduction about the origin of the subject, momentousness, partial contents and an overall review for the progresses as well as situations of 2D nanostructure, including 2D topological insulator nanostructures, titanium dioxide (TiO2) nanosheets, graphene and its nanocomposite. Chapter two reports a convenient hydrothermal intercalation/exfoliation method for large-scale manufacturing of bismuth telluride nanosheets. High quality Bi2Te3 nanosheets with thickness down to only 3 - 4 nm are obtained by removing lithium in the following exfoliating process. This hydrothermal intercalation/exfoliation method is general, as it has been extended to other layered inorganic materials. TiO2 nanosheet is a very important 2D nanostructure of metal oxide. Chapter three focuses on preparation of titania nanosheets by hydrothermal treatment. And a top-down path is illuminated to have an insight to the morphological evolution from nanoparticle to nanosheet by adjusting the concentrations of NaOH aqueous solution. The results of photocatalytic experiments indicate that the TiO2 nanobelts exhibit enhanced photocatalytic performance and suggest that the ph