三元及五元ⅰ2-ⅱ-ⅳ-ⅵ4族cu基化合物纳米晶的制备及其相关光电性能的研究-preparation of ternary and pentagonal ⅰ 2 - ⅱ - ⅳ - ⅵ 4 cu - based compound nanocrystals and their related photoelectric properties.docxVIP

Shanghai Shanghai Normal University Master of Philosophy Abstract 万方数据 万方数据 Abstract Nanocrystals have been discussed among various I2-II-IV-VI4 semiconductors many times, the quintuple nanocrystals also be prepared by doping method in order to study their optical properties in this experiment. The studies on NCs with different compositions are mainly focused on NCs’ optical properties, and linearly tuned band gaps. At the same time, quite deficient information on the electrical characteristic of wurtzite NCs has been released. In this experiment, wurtzite and kesterite NCs are produced by different anion sources in order to compare the electrical differences between the two compounds. In this thesis, the NCs are produced by hot-injection. Then dispersions of NCs in non-polar solvents can be directly applied onto (Mo)-coated soda lime glass substrates to form film samples. Then high-temperature sintering is used to remove oleylamine, and then their electrical properties are tested. After compared the two kinds of film samples, it is found that the electrical properties, including illuminated and dark current density, as well as Iphoton/Idark, are all higher for the hexagonal structure than the tetragonal one. The advantages conferred by the wurtzite structure can now be extended from certain compounds to all Cu2Zn(Sn1-xGex)S4 semiconductors, even possibly to the entire I2–II–IV–VI4 system, it provides references to study the application of their optical properties. When the lights, is incident or project, on the nanoparticles which constituted by noble metal element, if the frequency of the incident photon matches the overall vibration frequency of noble metal nanoparticles or metal islands conduction electrons, they would have a very strong photon energy absorption, and hence leads to the Localized Surface Plasmon Resonance (LSPR). Several semiconductor nanocrystals (NCs), such as binary copper chalcogenides CuxSy, WO3-, AZO, tin-doped indium oxide (ITO), and GeTe,