水性环氧树脂合成新工艺及性能研究-study on new synthesis process and properties of waterborne epoxy resin.docxVIP

水（TED）。固化剂用量均为15%时，TED体系初始固化温度为55℃，TETA固化体系的固化反应的初始温度降低到31℃，最大固化速率温度相应从115℃降低到102℃，完全固化温度从186℃降低到165℃。当PEG分子量从400增加到1000，水性环氧树脂固化反应的初始温度从31℃增加到34℃，最大固化速率温度相应从102℃增加到106℃，最终固化温度从165℃增加到172℃。3.本文对合成产物的性能进行了研究。运用三种脂肪族多元胺类固化剂（乙二胺、三乙烯四胺、三乙烯二胺六水）对自制的水性环氧树脂进行了固化研究，对固化产物的耐腐蚀性、耐水性、吸水性进行了测试，通过红外光谱（FTIR）对固化产物进行了表征。结果表明：三乙烯四胺的固化效果最好，乙二胺次之，三乙烯二胺六水最差；固化产物的耐碱性能较为突出，其它方面有待改进；由固化产物的红外光谱图可以看出，910cm-1附近的环氧特征吸收峰都大为减弱或消失，表明树脂已与固化剂发生交联反应。关键词：水性环氧树脂制备固化动力学ANewSynthesisTechnologyforWaterborneEpoxyResinandstudyofitsPerformanceIntroductionoftheauthor:ZangTianShun,male,wasborninAugust,1982whosetutorwasProfessorWanTao.HewillgraduatefromChengduUniversityofTechnologyinanalyticalchemistrymajorandbegrantedtheMasterDegreeinJune,2010.AbstractEpoxycoatinghasexcellentperformance,suchasgoodcorrosionresistance,chemicalresistance,adhesion,insulationresistance,highmechanicalstrength,andsoon.Itcouldbecuredbyavarietyofcuringagentwithstrongadhesiontosubstratebywayofflexibleanddiversifiedformulaaccordingtoneedinpractice.Becauseoftheseexcellentpropertiesofepoxycoating,itplaysadecisiveroleinthepaintindustryandhasbecomethemostwidelyusedcoatingresinscurrentlyandaccountsforabout40%ofitsproductioneachyearintheworld,mostofwhichareusedasanti-corrosioncoating.Atpresentepoxycoatingismainlysolvent-bornecoatingswithhighperformance.HoweverOrganicsolventsmaycauseenvironmentalpollutionwhenepoxycoatingisused,sodevelopmentofenvironmentallyfriendlyepoxyresinproductshasbecomeaconsensusduetotheincreaseinhumanawarenessofenvironmentalprotection.Water-basedmaterialswithnon-toxic,tasteless,pollution-freeadvantageshavebecomethemostrapidlygrowingandmostwidelyusedproductsinenvironment-friendlymaterials.Asthesubstratematerialofwater-basedmaterials,waterborneepoxyresinhasmanyuniqueadvantagesofitsown,suchaseasinesstouse,nofirehazard,noenvironmentalpollutionandsoon.Thepapersynthesizeswatersolubleepoxyresinwithusetwo-stepreaction,thefirststep-ring-openingreactionandthesecondstep-ring-closedreaction.Factorsaffectingthetwo-stepreactionhavebee