水性油墨丙烯酸酯聚氨酯乳液的合成与性能分析-synthesis and performance analysis of waterborne ink acrylate polyurethane emulsion.docxVIP

ABSTRACTThepolyester-polyesterdiolswaterbornepolyurethanedispersionwaspreparedbyprepolymerizationinthispaper.Andtheperformanceofpolyurethane-acrylate(PUA)dispersionwaspreparedbyacrylicestermodifiedpolyether-polyesterdiolspolyurethane.Thebinderofinkwasusedbythisemulsion.ItsvariouspropertiesofPUAbasedinkwereachievedtotheperformancerequirementsandanalysisontheinkviscosity,glossandotherinfluencingfactors.Themaintasksofthispaperembracethefollowingthreeaspects:Thereactionconditionwasdeterminedandtheratioof-NCO/-OH,theratioofpolyether-polyesterdiols,theeffectsofcarboxylcontent,thecrosslinkercontent,Influenceoftheneutralizationdegree,thereactiontemperature,thereactiontimeandshearratioonthepropertiesofemulsionandadhesivewereresearched.Theoptimalsynthesisparametersofthepolyester-polyesterdiolswaterbornepolyurethanearethatthetemperatureofpre-polymerizationreactionis65℃,thetimeis120min;thechainextenderreactiontimeis150minatabout78℃;thetemperatureofneutralizationreactionis20minatabout30~35℃whentheshearratiois1500~2300r/min.Theratioof-NCO/-OHwas1.13~1.27,theratioofpolyether-polyesterdiolswas25/75~35/65,thecarboxylcontentwas1.7~2.0%.Thecontentofcrosslinkeris1~2%.ThecategoryofneutralizerwasTEAandthedegreeofneutralizeris100~110%.Thereactionconditionacrylicestermonomermodifiedpolyether-polyesterpolyurethane,thereactionconditions,initiator,buffer,polyacrylate(PA)concentrationandmonomerratioonpolyurethaneacrylate(PUA)emulsionandfilmproperties.Theconditonofacrylicpolyurethaneemulsionprocessparameters:temperature80~85℃,theinitiatorconcentrationof0.45%,anappropriateamountofbuffer,stirringrateof300~500r/min,PAmonomerreactants18~28%ofitsmonomer:hydroxyethylmethacrylateesters(HEMA)inthedosageof1.9~2.4%,BA(butylacrylate)oftheamountof8.8~10.0%,methylIIImethacrylateester(MMA)amountof9.6~11.1%,Laurylacrylate(LA)contentwas4.0%,PUAfilm-formingtemperatureis100andtime130minutes.Studymechanicalstabilityforce,temperature,pHvalueontheacrylicpolyurethanehybridemulsionstability.Topolyetherpolyurethane,po