石墨烯负载锂镍钒氧的制备及电化学性能分析-preparation and electrochemical performance analysis of graphene-supported lithium, nickel, vanadium and oxygen.docxVIP

材料的比表面积，提高了材料与电解液的接触面积，也为锂离子的大量嵌入提供了更多的活性位置。材料的首次放电和充电的比容量分别高达912mAh/g和782mAh/g，首次库伦效率85.7%。经过27次循环之后，库伦效率稳定在95%以上。从循环伏安曲线上可以看到，经过5次循环后，材料对应的循环伏安曲线基本重合，表明经过循环伏安后材料的结构基本保持不变，这表明该电极材料具有良好的循环性能。以上说明了该实验条件下制备的石墨烯负载LiNiVO4非常适合作负极材料。关键词：石墨烯水热法锂离子电池锂镍钒氧负极材料IIAbstract:Inrecentyears,withthedevelopmentofportabledevicesandelectricvehicles,lithiumionelectrodematerialswithexcellentelectrochemicalperformancehaveattractedmoreandmoreattention.Amongthem,LiNiVO4withthespinelstructureisreceivingincreasingattentionduetoitsexcellentcycleperformance,highvoltageplatform.However,thedevelopmentoftheLiNiVO4materialisrestrictedbythesefactorssuchaslowspecificcapacity,highdiffusionimpedance,andtheperformanceinfluencedbythedifferentpreparationmethods.Theelectronmobilityofthenovelgraphenecanbeupto2×105cm2/V·s,thethermalconductivityisupto5000W·m-1·K-1;thespecificsurfaceareais2630m2·g-1.Studiesshownthatthepresenceofthegraphenecanimprovetheelectronicconductivityofthematerial,shortenthelithiumiondiffusionpath,andstabilizethematerialstructure.Thegrapheneasconductiveadditivescangreatlyimprovethecyclestabilityofthelithiumionbattery,largecurrentchargeanddischargeperformance,andsafetyperformance.Basedontheseproperties,thepreparationmethodofthenewLiNiVO4cathodematerialforlithiumionbatteryisexpectedtoimprovetheperformanceofthematerials.Inthispaper,LiNiVO4cathodematerialswerepreparedbysol-gelmethodandhydrothermalmethod,inwhichV2O5powder,H2O2,LiAcandNi(Ac)2·4H2O,hydrogenperoxide,graphitepowder,concentratedsulfuricacid,phosphoruspentoxideandglycolasrawmaterials.GraphiteoxidewaspreparedthroughtheimprovedHummersmethodandgraphenesupportedLiNiVO4wassynthesizedusinghydrothermalmethod.Themorphologyandstructureoftheas-preparedmaterialswerecharacterizedbyscanningelectronmicroscope(SEM),transmissionelectronmicroscope(TEM),X-raydiffraction(XRD),Fouriertransforminfraredspectroscopy(FT-IR).TheelectrochemicalperformanceofthematerialasanodeforLithium-ionbatterieswasstudiedbygalvanostaticcharge-discharge,cyclelifetesting,and