生物质微波预处理的实验分析-experimental analysis of microwave pretreatment of biomass.docxVIP

ABSTRACTItisclearthatgrowingbiomassisanexcellentmethodbywhichatmosphericcarbondioxidecanbesequestered,minimizingtheeffectofgreenhousegasesontheEarth’satmosphere.Itisasourceofsustainableenergyandhaspotentialtoplayanimportantroleinthefuturearoundtheworld.Butitsrelativelyhighmoisturecontent,lowcalorificvalueandothershortcomingsmeanthatitislessattractiveasafuelthancoalwhichhavemuchhigherenergydensy.Microwavetechnologyhasbeenshowntobeanenergy-efficientmethodforchemicalprocessingandhasbecomewidelyacceptedasamildandcontrollableprocessingtool.Lowtemperaturemicrowavepretreatmenthasrarelybeenreportedandtheobjectiveofthisresearchistoexplorethelowtemperaturemicrowavepretreatmentofcottonstalkandsawdust.Thefeasibilityofbiomasspretreatmentbycharacterizingsolidproductsforsucceedingprocesstogeneraterenewablefuels.Twoprocesseswereevaluated:dryingandpyrolysis.Inmicrowavedrying,temperatureisthemostimportantfactorsaffectingmicrowavedryingcharacteristics,biomassistreatedinthetemperaturerangeof80°C–140°C,thehigherdryingtemperature,thefasterthedryingrate,andmicrowavedryingcanalsoenrichbiomassporestructure,effectivelyincreasethespecificsurfaceareaofthematerials.Inlowtemperaturemicrowave-inducedpyrolysis,biomassistreatedwithnitrogen,at150°C–400°C.ThisprocesshappenedwiththereleaseofCO,CO2,CH4non-condensablegas,andliquidproductmainlycontainstheacid,alcohol,aldehydewhicharetheproductsofhemicellulosedecomposition.Inaddition,thisprocessproducedasolidproductwithenhancedfuelvalue,whichgetthesamevalueneededtemperature40℃lowerthantheconventionaltorrefaction.Lowtemperaturemicrowave-inducedpretreatmentofbiomasscouldbeacompetitivetechnologytoemploytheleastenergyandtoretainthemostbioenergy.Meanwhile,duetothesheddingofoxygencontainingfunctionalgroupsandtheescapeofgasandliquidcontainingoxygen,theO/Cratiosofsolidproductisverylow.IntegratedtechnologyIIandeconomyoflowtemperaturemicrowave-inducedpyrolysis,thisarticlegivesasuggestion:lowtemperaturemicrowave-inducedpyrolysisconditionsdonotexceed250℃,about20min.I