丙烯酸乙酯接枝淀粉及有机凝胶的制备论文.docVIP

PAGE PAGE \* MERGEFORMAT IV 本科毕业设计(论文) 题目：丙烯酸乙酯接枝淀粉及有机凝胶的制备 院（系） 材料与化工学院 专 业 　　高分子材料与工程 班 级 　　 姓 名 　 学 号 　 导 师 　 2013年6月 PAGE \* MERGEFORMAT 1 丙烯酸乙酯接枝淀粉及有机凝胶的制备研究 摘要 本论文以硝酸铈铵为引发剂，采用单体丙烯酸乙酯对可溶性淀粉进行表面接枝共聚，对可能对实验接枝率产生影响的因素如单体用量、引发剂用量、反应时间、反应温度进行了探讨。然后以改性淀粉为胶凝剂制备有机凝胶，并对凝胶进行了检测,探讨了表面活性剂用量、极性溶剂用量、搅拌速度、胶凝剂用量以及反应温度对凝胶形成的影响。 研究表明：经表面接枝改性的淀粉与有机溶剂的相容性增加，以改性后的淀粉作为胶凝剂，并在有机溶剂、表面活性剂以及极性溶剂存在下制备凝胶，在30℃，搅拌速度680r/min，表面活性剂1.5ml，0.5 关键词：淀粉； 丙烯酸乙酯； 接枝改性； 凝胶 Graft Copolymerization of Acrylic Acid Ethyl Ester onto Starch and Preparation of Organic gel Abstract In this paper，it use ceric ammonium nitrate as initiator，and the ethyl acrylate as the monomer to graft modification in soluble starch′s surface ,and investigating the factors that may influence the experiment such as the influences of the monomer, the initiator concentration, the reaction time and the reaction temperature to the graft yield; modified starch as a gelling agent to preparation of the organic gel, according to detect the gel to investigate the effect of the amount of surfactant，the polarity of the solvent，gelling agent and the stirring speed，the reaction temperature to the gel formation. Studies have shown that：the compatibility of the surface grafting modification starch and the organic solvent is increased. According to the modified starch as a gelling agent，organic solvent，surfactant and polar solvent to prepare the gel in 30℃，stirring speed as 680r/min and the surfactant for 1.3ml，the polar solvent for 3.0ml，by adding in gel for 0.5g in the system，the gel thermal stability is the best. Key words：starch； ethyl acrylate； graft modified； gel 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc 摘要 PAGEREF _Toc \h I HYPERLINK \l _Toc 1 绪论 PAGEREF _Toc \h 1 HYPERLINK \l _Toc 1.1淀粉的概述 PAGEREF _Toc \h 1 HYPERLINK \l _Toc 1.1.1淀粉简介 PAGEREF _Toc \h 1 HYPERLINK \l _Toc 1.1.2淀粉的基本结构 PAGEREF _Toc \h 1 HYPERLINK \l _Toc 1.1.