双子表面活性剂和普通表面活性剂增敏双硫腙吸光光度法测定茶叶中锌含量的对比 毕业论文suwir.docVIP

PAGE 双子表面活性剂和普通表面活性剂增敏双硫腙吸光光度法测定茶叶中锌含量的对比 化学化工学院化学教育专业 摘要：本文研究了在常温下，双子表面活性剂16-0-16和普通表面活性剂CTMAB对可见分光光度法测定锌(Ⅱ)的增敏作用，考察了最适波长选择、显色时间的选定、最适PH的选取、缓冲剂的用量以及表面活性剂用量对测定茶叶样品中锌(Ⅱ)的影响。据此建立了测量锌(Ⅱ)的方法。在双子表面活性剂16-0-16存在时pH＝12.03条件下，在锌离子浓度0.0~4.0mg/L的范围内遵守比尔定律，其线性方程为Y=0.34+0.28143C，R2=0.99854，ε=4.06×104 L·cm-1·mol-1, DL=0.62mg/L, 样品测定相对标准偏差为0.48%，回收率为96.05～99.25%。在CTMAB存在时pH=10.00条件下, 在0.0~8.0mg/L的范围内遵守比尔定律，其线性方程为Y=0.43822+0.0296C，R2=0.99731，ε=3.05×104 L·cm-1·mol-1, DL= 0.81 mg/L，样品测定相对标准偏差为0. 关键词：双子表面活性剂;锌;双硫腙;茶叶;分光光度法 A Comparison of Sensitivity Enhancement by Gemini and by Commercial Surfactants in the Determination of Zinc in Tea by Dithizone Spectrophotometry Tang xumei Chemistry and Chemistry Engineering Grade 2005 Instructor: Jiang xiaohui Abstract: The sensitivity enhancement of 16-0-16 gemini surfactant and that of commercial surfactant CTMAB was compared in the spectrophotometric determination of zinc(Ⅱ) with dithizone as colorant. The parameters such as of znic(Ⅱ) system at normal temperature and investigates which surfactants is suit for this reaction and the best reaction time, the volume of surfactant, buffer solution. Base on the above principle, we established a novel method which use gemini surfactants 16-0-16, at PH=12.03 determine traces of Znic(Ⅱ). In the 0.0 ~ 4.0mg/L to comply with the framework of Beers law is obeyed, the linear equation Y=0.34+0.28143C，R2=0.99854，ε=4.06×104 L·cm-1·mol-1, DL = 0.62mg/L, the relative standard deviation of the method is 0.48%, recovery is 96.05～99.25%. At CTMAB, PH=10.00 determine traces of Znic(Ⅱ), in the 0.0 ~ 8.0mg/L to comply with the framework of Beers law is obeyed, the linear equation Y=0.43822+0.0296C，R2=0.99731，ε=3.05×104 L·cm-1·mol-1, DL = 0.81mg/L, the relative standard deviation of the method is 0.78%, recovery is 94.65 ~ 96.85%. Key words: gemini surfactants ; Zinc ; dithizone ; tea ; Spectrophotometry 1 前言 1.1表面活性剂的历史发展 　　表面活性剂和合成洗涤剂形成一门工业得追溯到本世纪30年代，以石油化工原料衍生的合成表面活性剂和洗涤剂打破了肥皂一统天下的局面。经过60余年的发展，1995年世界洗涤剂总产