酯基型双子表面活性剂地合成及驱油性能.docxVIP

酯基型双子表面活性剂的合成及驱油性能 李小瑞，解颖，王海花*，沈一丁，费贵强，廖勇 （陕西科技大学 教育部轻化工助剂化学与技术重点实验室，陕西 西安 710021） 摘要：采用丁二酸酐、N,N-二甲基乙醇胺和溴代烷CnH2n+1Br（n=10、12、14、16、18）通过两步反应制备了含酯基的阳离子双子表面活性剂〔简称为GSn-EG-n(n=10、12、14、16、18)〕。利用FTIR、1HNMR对产物结构进行表征，用表面张力仪、电导率仪、荧光光谱仪（FLD）、光学接触角测量仪和界面张力仪对产物的溶液性质进行测定。结果表明，随着碳链长度的增加，表面活性剂越易聚集缔合成胶束，GS18-EG-18临界胶束浓度（CMC）最低达到2.14×10-5mol/L，GS14-EG-14溶液的表面张力最低降至33.50mN/m。通过测定不同温度下溶液的电导率，发现其CMC值随着温度的升高而增大。乳化性和润湿性测试结果表明，GS14-EG-14乳化系统中，油/水分离时间达到180min，且在聚四氟乙烯板（简称PTFE）上的接触角为69.3o，说明GS14-EG-14具有很好的乳化性能和润湿性能。GS18-EG-18仅用28min可以将油/水界面张力降低至8.3×10-3mN/m，而且最终驱油效率达54.2%。 关键词：Gemini双季铵盐表面活性剂；酯基；乳化性；润湿性；驱油 Synthesis and Oil Displacing Capacity of Gemini Surfactants with Ester Group LI Xiao-rui, Xie Ying, WANG Hai-hua*, SHEN Yi-ding, FEI Gui-qiang, LIAO Yong (Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science Technology, Xi’an 710021, Shaanxi, China) Abstract: A series of biquaternary ammonium salt gemini surfactants with ester group was prepared with succinic anhydride,N,N-dimethylethanolamine,CnH2n+1Br (n=10,12,14,16,18) as raw materials.The structure of the obtained product were characterized by FTIR, 1HNMR and its solution properties were investigated with surface tensiometer, conductivity meter, fluorescence spectroscopy (FLD), optical contact angle measuring device and interface tensiometer. The results show that with the increase of hydrophobic chain length, the surfactants easily associated and aggregated to gether to form micelles, and the critical micelle concentration (CMC) of GS18-EG-18 decreased to 2.14×10-5mol/L. The minimum surface tension (γCMC) of 33.50mN/m was determined for GS14-EG-14. Moreover, by measuring the conductivity of the solution at different temperatures, it was found that the CMC value increased with the increase of temperature. The emulsification and wettability tests demonstrated that oil and water separation time of 180min in the emulsion system for GS14-EG-14, and its minimum cont