噻吩磺隆水解光解行为分析.docVIP

噻吩磺隆水解光解行为分析 　　摘要：采用室内模拟试验研究了噻吩磺隆水解及光解行为，以期为环境和生态安全性评价提供科学依据。土壤样品经乙腈提取，水样经二氯甲烷提取，高效液相色谱仪（DAD检测器）检测。结果表明，噻吩磺隆在不同pH缓冲溶液中水解速率大小依次为pH 4.0、 pH 9.0、pH 7.0，在25 ℃、pH 7.0时，其半衰期最长，达2 310.49 h（96.27 d）;噻吩磺隆在纯水中的光解半衰期为2.30 h，土表光解试验在7 d内，光照下光解速率与黑暗状态下无显著差异。温度和pH对噻吩磺隆的水解有显著影响。根据《化学农药环境安全评价试验准则》划分标准，噻吩磺隆水解特性属易水解和较难水解，水中和土表光解特性属易光解和难光解。 　　关键词：噻吩磺隆;水解;光解 　　中图分类号：TQ450.2 文献标识码：A 文章编号：0439-8114（2015）23-5862-04 　　DOI：10.14088/j.cnki.issn0439-8114.2015.23.017 　　Environmental Behaviors Including Hydrolysis，Photolysis of Thifensulfuron-methy 　　LI Xin-an，LI Guang-ling，LI Song-wei，GU Shan-shan，CHEN Xi-ling 　　（College of Resources and Environment，Henan Institute of Science and Technology，Xinxiang Henan 453003，china） 　　Abstract： To supple the scientific evidence of the environment and ecological safety， environmental behaviors including hydrolysis， photolysis of thifensulfuron-methy were studied by laboratory simulation. Soil samples were extracted with acetonitrile， and water samples were extracted by dichloromethane， both of them were detected by reversed-phase HPLC with an ultraviolet detector. The results showed that hydrolysis rate of thifensulfuron-methy in different buffers was pH 4pH 9pH 7，and the half-life of thifensulfuron-methy was the longest when the tempreature was 25 ℃， pH was 7， up to 2 310.49 h（96.27 d）. The photolytic half-life of thifensulfuron-methy in pure water was 2.30 h. The result of soil surface photolysis test in 7 days showed that its photolysis rate in illumination had no significant differences with that in dark. Temperature and pH had significantly influence on the hydrolysis of thifensulfuron-methy. Based on the dividing standard of guidelines on environmental safety assessment for chemical pesticides， thifensulfuron-methy was easily and difficult to hydrolyze， very easy in pour water and difficult in soil surface to photolyze. 　　Key words：thifensulfuron-methy;hydrolysis; photolysis 　　噻吩磺隆（Thifensulfuron-methy）是由杜邦公司开发的一种磺酰脲类除草剂，其化学名称为3