刚果红-巯基棉分离富集光度法测定垃圾渗滤液中镉-环境监测管理与技术.PDFVIP

20 1 2008 2 - 江虹, 吕昕, 何树华 (长江师范学院化学及环境科学系,重庆 408003) : pH 4. 0~ 5. 2 BR, , 604 nm 492 nm, 0. 10 mg/L~ 2. 80mg/L 0. 10mg/L~ 3. 40 mg/L, , , , 98. 6% ~ 104% : ;; ;; : O657. 32 : B : 2008) 01- 0029- 04 Th e D eterm ination of Cadm ium in Landf ill Leachate by Congo R ed and Sulfhyd ryl Cotton P reconcen traction Spectrophotom etry JI NG Hong, LV Xin, HE Shuhua (D ep artm ent of Chem istry and Env ironm ental S cience, Yang tz e N orm al Colleg e, Chong q ing 408003, Ch ina ) Abs tract: Cadm ium ( ) reactsw ith congo red to form blue ion complexes in the BR pH 4. 0~ 5. 2 buffer solution. method was established for determ ination of cadm ium in landfill leachate by spectrophotometry w ith sulfhydryl cotton preconcentraction. Themaxmi um positive absorption wavelength was at604 nm and maxmi um negative absorption wavelengthwas at492 nm. The linearities ranged from 0. 10 mg/L to 2. 80 mg/L( positive absorption) and from 0. 10 mg/L to 3. 40mg/L( negative absorption). Them ethod was sensitive at the positive and m inuswavelengths overlapping absorption. The treatment of landfill leachate and interference of coexistent ion were discussed. The analytical parameterswere optmi ized. The samples detective results of them ethod were on differentw ith the results of atom ic absorption spectrom etry. The recoverieswere 98. 6% ~ 104%. K ey w ord s: Cadm ium; Congo red; Sulfhydryl cotton; Spectrometry; Landfill leachate , , 1 , , 1. 1 主要仪器与试剂 U- 4100- -, [ 1- 4] ; H I 9204,