以酚液化相思树为基质Novolak型酚甲醛树脂含浸木粉制造成型板.PDF

32(4) 61-70, 2010 61 林業研究季刊 ： 研究報告 以酚液化相思樹為基質Novolak 型酚甲醛樹脂 含浸木粉製造成型板性質之研究 1 2 2 3 謝漢民 張國峻 許玲瑛 李文昭 H2 SO4 HCl 【摘要】本研究將相思樹木材以酚為溶劑， 及 為催化劑進行液化處理，所得酚液化相思 樹與福馬林在甲醇溶液中進行反應製備S-PF 及H-PF 兩種Novolak 型酚甲醛(PF) 樹脂溶液，並將 其含浸至麻六甲合歡木粉形成樹脂含浸木粉。由 DSC 熱分析顯示含浸至木粉之乾燥樹脂具熱熔融 性，混合六甲基四胺為架橋劑則具備熱硬化性。兩種樹脂含浸木粉混合六甲基四胺後可熱壓製造成 型板，其中以H-PF 樹脂含浸木粉所製造者其內聚強度及浸水尺寸安定性優於以S-PF 樹脂含浸者， 200 10 min 12 min TGA 在 ℃熱壓溫度下，熱壓時間 者優於熱壓時間 者； 熱分析顯示在相同熱壓溫 度下，兩種樹脂含浸木粉所製作成型板具有相似之熱裂解行為，然熱壓時間 12 min 者之耐熱性則 優於熱壓時間10 min 者。 Novolak 【關鍵詞】相思樹、液化木材、成型板、 型酚甲醛樹脂、樹脂含浸木粉 Research paper Study on the Properties of Moldings Made with Wood Powders Impregnated with Phenol-liquefied Acacia Confusa Based-novolak Phenol-Formaldehyde Resins Han-Min Hsieh1 Kuo-Chun Chang2 Ling-Ying Hsu2 Wen-Jau Lee3 Abstract Wood of Acacia confusa Merr. (Taiwan acacia) was liquefied in phenol with H2 SO4 and 【 】 HCl as catalysts. Two kinds of solution-type novolak phenol-formaldehyde (PF) resin, S-PF and H- PF, were synthesized by reacting liquefied Taiwan acacia with formalin in methanol. After then, Albizzia falcate wood powders were immersed in these resins to form resin impregnated wood powders. DSC analysis showed that the dried resin that impregnated in wood powders had the behavior of thermo-melting, and had the capability of thermo-setting when mixing with hexamethylenetetramine 1. 國立中興大學森林學系碩士生 Graduate Student, Department of Forestry, National Chung-Hsing University, ROC 2. 國立中興大學森林學系碩士 Master, Department of Forestry, National Chung-Hsing University, ROC