组成和催化剂对li-mg-n-h体系储氢材料性能的影响-effect of composition and catalyst on properties of li - mg - n - h hydrogen storage materials.docxVIP

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组成和催化剂对li-mg-n-h体系储氢材料性能的影响-effect of composition and catalyst on properties of li - mg - n - h hydrogen storage materials.docx

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组成和催化剂对li-mg-n-h体系储氢材料性能的影响-effect of composition and catalyst on properties of li - mg - n - h hydrogen storage materials

iii iii 组成和催化剂对 Li-Mg-N-H 体系储氢材料性能的影响 activation energy of the desorption reaction can be calculated , the value of Ea of the former is 42.5kJ/mol, and that of the latter is 51.7kJ/mol. The difference is that the former system has MgH2 left, and the latter system has LiH left. The absorption and desorption capacity of the former system is slightly stronger than the catalytic ability of the latter. However, the ability of inhibition ammonia released for LiH is stronger than that of the former, because lithium hydride and ammonia reaction is faster than that of magnesium hydride. (3) After 50 hours by high-energy ball milling, the particles of CaCO3 can be reduced into nanometer, and its size can reached about 100nm. The equilibrium pressure of Li-Mg-N-H system can not be changed after mixing nanometer CaCO3 catalyst, but the absorption and desorption kinetics of the system is obviously increased. It is showed that after CaCO3 was mixed into the system as a catalyst, the viscosity of the sample was reduced, and the contact area among the particles were increased, so the reaction rate became faster. Keywords: High-energy Ball milling; Li-Mg-N-H hydrogen storage system; dehydrogenation and hydrogenation kinetics performance; p-c-T curves; catalyst 目录 HYPERLINK \l _bookmark0 第一章绪论 1 HYPERLINK \l _bookmark1 1.1 引言 1 HYPERLINK \l _bookmark2 1.2 氢能 2 HYPERLINK \l _bookmark3 1.2.1 氢能的特点 2 HYPERLINK \l _bookmark4 1.2.2 氢能的开发与制氢技术 3 HYPERLINK \l _bookmark5 1.2.3 储氢技术 4 HYPERLINK \l _bookmark6 1.2.4 氢的运输技术 7 HYPERLINK \l _bookmark7 1.2.5 氢能的利用 7 HYPERLINK \l _bookmark8 1.3 储氢材料 8 HYPERLINK \l _bookmark9 1.3.1 储氢材料的定义 8 HYPERLINK \l _bookmark10 1.3.2 储氢材料的性质 8 HYPERLINK \l _bookmark11 1.3.3 储氢材料的分类 8 HYPERLINK \l _bookmark12 1.4 本文的研究内容及技术路线 18 HYPERLINK \l _bookmark13 第二章实验方法 19 HYPERLINK \l _bookmark14 2.1 实验原料 19 HYPERLINK \l _bookmark15 2.2 实验设备 19 HYPERLINK \l _bookmark16 2.3 实验材料的制备 20 HYPERLINK \l _bookmark17 2.4 仪器分析 22 HYPERLINK \l _bookmark