包钢转炉渣微波碳热还原脱磷研究-冶金工程专业论文.docxVIP

内蒙古科技大学硕士学位论文 III a peak dephosphorus rate, show that there is an optimum ratio of carbon equivalent; The first steelmaking slag as briquetting,the vacuum degree under 0.01 atm, the carbon equivalent is 2~3 times, dephosphorus rate is higher, about 34%;The low granularity, low pressure, increasing holding time are conducive to the reduction reaction and dephosphorization rate. At particle size of 0.075mm, 3Ceq, temperature 1300 C, holding 30 mints,the vacuum degree under 0.01 atm and the dephosphorization rate of the first steelmaking slag could up to 34.31%.And take the pressure, powdery of converter steel slag block two (under the same condition as a steel slag tested). On the basis of thermodynamic calculation, kinetic experiments of dephosphorization reaction are conducted. To analysis the experimental data, the fact that the dephosphorization reaction is two order reactions is found and the reaction activation energy is 55.516KJ/mol. Therefore, the restrictive aspects of this reaction are the chemical reaction interface. The results of this paper can provide theoretical guidance for the converter slag recycling utilization and achieving zero emissions of by product. Key Words: Converter slag；Microwave Technology；Gasification dephosphorization； Thermodynamics；Dynamics  PAGE 3 目 录 摘 要I AbstractII 引 言 1 1 文献综述 2 1.1 转炉钢渣还原脱磷的研究进展 2 1.1.1 研究背景及我国钢渣现状 2 1.1.2 转炉钢渣的处理与利用现状 2 1.1.3 转炉钢渣循环利用价值 6 1.1.4 转炉钢渣还原脱磷技术研究现状分析 7 1.2 钢渣的组成、性质及渣中磷的分布状态 10 1.2.1 钢渣的组成及其来源 10 1.2.2 磷在钢渣中的存在形式及分布状态 12 1.3 微波技术的发展及在冶金领域的研究与应用13 1.3.1 微波技术的发展历程 13 1.3.2 微波加热基本原理及特点 14 1.3.3 微波加热技术在冶金领域的应用15 1.4 碳热还原 P2O5 的动力学基础 16 1.4.1 钢渣中氧化物的还原 16 1.4.2 钢渣脱磷反应的动力学机理分析18 1.4.3 气化脱磷的物理模型 18 1.5 选题目的及意义 19 2 实验内容、方案与分析方法 21 2.1 实验内容与设备 21 2.2 实验方案及原料 23 2.3 分析测试方法 25 3 转炉钢渣气化脱磷的热力学研究26 3.1 Ca3(PO4)2 与 C 反应生成 P4 的热力学计算 26 3.1.1 不添加 SiO2 条件下气化脱磷反应热力学 26 3.1.2 添加 SiO2 条件下气化脱磷反应热力学 27 3.1.3 脱磷反应热效应计算 28 3.2 采用纯试剂进行热力学实验验证分析29 3.2.1 气化脱磷反应开始温度及压力条件的确定 29 3.2.2 钢渣气化脱磷反应温度范围的确定 31 4 碳热还原钢渣气化脱磷的影响因素 3