胺类有机物阻燃eps保温板研究-材料学专业论文.docxVIP

中北大学学位论文 万方数据 对 EPS 阻燃更 有效 。阻燃 机理不 同， 导 致试样 燃烧后 形貌 不 同。 NH4Cl/CMC 和 (NH4)2SO4/CMC 为气相阻燃，其氧指数试样燃烧后残炭结构松散，建筑材料可燃性试样 燃烧后残炭保持了阻燃剂的分布结构。NH4H2PO4/CMC 和(NH4)2HPO4/CMC 为膨胀阻燃， 其氧指数试样燃烧后残炭多而质密，建筑材料可燃性试样燃烧后残炭为团状和丝状。 （4）热重分析显示，随着升温速率的增大，四种阻燃 EPS 均存在热滞后现象，失 重 5%的温度都比纯 EPS 提前，600℃时的残留比纯 EPS 有大幅提升。Flynn-Wall-Ozawa 法用于计算 EPS 和四种阻燃 EPS 的降解活化能，均具有较高的相关系数，Kissinger 法 计算的(NH4)2HPO4/CMC 阻燃 EPS 相关性较差，但对其它三种阻燃 EPS 和纯 EPS 适用。 阻燃剂不同，阻燃机理不同，降解活化能和降解活化能变化趋势有区别。 关键词：聚苯乙烯泡沫、阻燃、氯化铵、硫酸铵、磷酸氢二铵、磷酸二氢铵  The study on the Flame Retardant Polystyrene Foam Board using Organic Amine Abstract With the implementation of the national energy conservation policies ， expanded polystyrene（EPS）has been widely used as exterior wall materials of buildings. But it has a potential fire hazard for its flammable properties. But the current commercially available mainly use HBCD and expanded graphite as flame retardants. Therefore, it is necessary to develop a new kind of flame-retardant EPS board with excellent flame retardant properties which is low-cost, simple and market acceptable. In this paper, different organic amines were used to modify the flame retardant property of buildings exterior EPS insulation board. Ammonium chloride（NH4Cl）， ammonium sulfate（(NH4)2SO4）, ammonium dihydrogen phosphate（NH4H2PO4）and diammonium phosphate （ (NH4)2HPO4 ） were formulated into solutions of different concentrations, respectively. 2.0wt% of carboxymethylcellulose sodium (CMC) was added into solutions as thickening agents, binder and carbon source. Then，the EPS board was fire-retardant solution soaked and flame-retardant EPS was obtained. The influence of the type and content of flame retardants on the flame retardant properties of EPS were investigated by oxygen index test and building materials flammability test. The residual carbon morphology was studied by scanning electron microscope(SEM). And the thermal properties of flame retardant EPS were studied by thermogravimetry. The degradation activation energies wer