丙烯酸酯的原子转移自由基共聚合研究高分子化学与物理专业论文.docx

重庆大 重庆大学硕士学位论文 英文摘要 PAGE PAGE VI ABSTRACT Copolymerization of methyl methacrylate(MMA) and 2-hydroxyethyl methacrylate (HEMA) was studied in emulsion by atom transfer radical polymerization (ATRP). The emulsion atom transfer radical copolymerization of MMA and HEMA was carried out with Tween-80 as surfactant ,benzyl bromide as an initiator and CuBr/CuBr2/bpy（2，2＇-bipyridine）(or dNbpy (4，4＇-dinonyl-2，2＇-bipyridine) or phen (o-phenanthroline) or PMDETA (N ， N ＇， N ＇， N ， N-pentamethyldiethylenetriamine)) as a catalyst system, and its influencing factors was discussed, and the best formula was obtained by experiments, and the copolymer of MMA and HEMA that made by the formula is tested by GPC, IR, NMR and hydroxyl value analysis. ATRP of two different ways of the added reactants was compared, the effects of ways of the added reactants was analyzed by total conversion of monomer. It is beneficial to polymerization that the oil-soluble initiator was added preceding to catalyst system and emulsion is precasted and the reaction occurred by catalyst system, because the initiator is easy into micelle. If the other reactants was added and emulsion is precasted and the reaction occurred by the initiator, then possibly initiator occurred more side-reaction, polymerization may be difficult or slow to carry out. When the reaction temperature is changed at different experiments, the polymerization rate increases depending on temperature, but the linear relationships of ln([M]0/[M])～t in polymerization is impacted. When proper ligand is used, the linear relationships of ln([M]0/[M])～t is better, the intrinsic viscosity of the polymer solution increases depending on monomer conversion, and the controlled characteristic is better. Polymerization can occur at wider temperature range when dNbpy is as ligand, and the reactions have the controlled characteristic; just the oil-soluble ligand is more beneficial to control the emulsion ATRP. When the ligand proportion incr