毕业论文设计《717强碱阴离子交换树脂对苯酚的吸附特性》.doc

玉林师范学院本科生毕业论文 717强碱阴离子交换树脂对苯酚的吸附特性 717 strong base anion exchange resin adsorption characteristics of phenol 院 系 专 业 学 生 班 应化 姓 名 号 化学与生物系 指导教师姓名 指导教师职称 教授 717强碱阴离子交换树脂对苯酚的吸附特性 摘要 采用静态法研究了717强碱阴离子交换树脂对苯酚的吸附性能，考察pH值、浓度、吸附时间、温度等对吸附量的影响，并对吸附的动力学和热力学进行了初步探讨。实验结果表明，717强碱阴离子交换树脂对苯酚的吸附在pH=10~13范围内，吸附能力最好，具有较大的吸附容量和较快的吸附速率；等温吸附能较好的吻合Langmuir和Freundlich经验方程，表现为优惠吸附。热力学分析表明，该吸附为放热熵减的自发过程。吸附动力学可用Lagergren准二级吸附速率方程描述，符合HSDM模型，以颗粒内扩散为主控步骤，同时也受液膜扩散影响。通过实验测得303K时树脂对苯酚的静态饱和吸附容量为399.8mg/g （即4.253mmol/g）。 关键词：苯酚，717阴离子交换树脂，吸附，热力学，动力学 717 strong base anion exchange resin adsorption characteristics of phenol Applied Chemistry 2005 He Xing-rong Supervisor Xie Zu-fang Abstract In this study, 717 strong base anion exchange resin adsorption properties of phenol was studied by static method, investigated pH, concentration, adsorption time, temperature and so on, the effects of adsorption and adsorption kinetics and thermodynamics were discussed. Experimental results show that the 717 strong base anion exchange resin adsorption of phenol at pH = 10 ~ 13 range, the adsorption capacity of the best and have greater capacity and faster adsorption rate of adsorption; adsorption isotherm can be better with Langmuir experience and Freundlich equation for the preferential adsorption performance. Thermodynamic analysis shows that the adsorption is exothermic by the spontaneous process of entropy. Adsorption Kinetics of available quasi-two Lagergren adsorption rate equation, consistent with the HSDM model for particle diffusion control steps, but also by the spread of the impact of film. Measured by experiment at 303K phenol resin static saturated adsorption capacity of 399.8mg / g (that is, 4.253mmol / g). Key words: Phenol，717 anion exchange resin，adsorption ，thermodynamics， kinetics 目录 1.前言 1 1.1苯酚 1 1.1.1苯酚的性质及用途 1 1.1.2苯酚工业废水 1 1.1.3含酚废水的处理方法及研究实例 2 1.2离子交换树脂 4 1.2.1离子交换树脂的结构与特点 4 1.2.2离子交换树脂的分类 5 1.2.3离子交换树脂吸附的原理 5 1.2.4离子交换动力学原理 5 1.2.5离子交换树