Pd-SiWSiO催化乙烯气相直接氧化制乙酸SiO孔结构的影响.docVIP

Pd-SiWSiO催化乙烯气相直接氧化制乙酸：SiO孔结构的影响 第 30 卷 第 10 期 催 化 学 报2009年 10月 Vol. 30 No. 10 Chinese Journal of Catalysis October 2009 文章编号: 0253-9837200910-0976-05 研究论文: 976~980 Pd-SiW /SiO 催化乙烯气相直接氧化制乙酸:SiO 孔结构的影响 12 2 2 1, 2 1, 2 1 1 徐庶亮 , 王丽霞 , 楚文玲 , 杨维慎1 中国科学院大连化学物理研究所催化基础国家重点实验室, 辽宁大连 116023 2 中国科学院研究生院, 北京 100049 摘要:采用三种不同孔结构的 SiO 制备了 Pd-SiW /SiO 催化剂, 通过 X 射线衍射、N 物理吸附、吡啶吸附红外光谱以及 H 脉 2 12 2 2 2 冲化学吸附对催化剂进行了表征, 并考察了 Pd-SiW /SiO 催化剂上乙烯直接氧化制乙酸反应性能结果表明, 以孔径较大的粗 12 2 孔硅胶为载体制备的 Pd-SiW /SiO 催化剂显示出最高的催化活性, 乙酸收率为 145.2 g/L?h这是由于 Pd 在粗孔硅胶载体表面 12 2良好的分散使其具有较高的催化活性 关键词:钯; 硅钨酸; 硅胶; 乙烯; 氧化; 乙酸 中图分类号:O643文献标识码:AEffect of Pore Structure of SiO on Catalytic Performance of Pd-SiW /SiO for 2 12 2 Direct Oxidation of Ethylene to Acetic Acid 1, 2 1, 2 1,* 1,* XU Shuliang , WANG Lixia , CHU Wenling , YANG Weishen 1 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China 2 Graduate University of Chinese Academy of Sciences, Beijing 100049, China Abstract: The Pd-SiW /SiO catalysts with different pore structure of SiO were prepared for direct oxidation of ethylene to acetic acid. The 12 2 2 catalysts were characterized by X-ray diffraction, N physical adsorption, infrared spectroscopy of adsorbed pyridine, and H -pulse chemical 2 2 adsorption. The results showed that the pore structure of SiO had an important influence on the catalytic performance of the catalysts. The 2 Pd-SiW /SiO catalyst prepared by the SiO support with larger pore size and pore distribution exhibited the highest catalytic activity, on 12 2 2 which 145.2 g/L?h of acetic acid yield was obtained. Pd dispersion was responsible for the catalytic activity of the Pd-SiW /SiO catalyst12 2 Key words: palladium; silicotungstic acid; silica; ethylene; oxidation; acetic acid 乙酸是一种重要的基础有机化工原料, 主要用 日本昭和电工株式会社开发的乙烯气相直接氧 于生产醋酸纤维、醋酸乙烯及制药、染料、农药以 化制乙酸的新工艺, 在 1997 年率先实现了年产十万 [1] [3~6] 及用作众多有机合成的原料与溶剂 目前, 生产乙 吨乙酸生产装置的工业化 其技术核心