电化学耦合膜工艺去除饮用水中卡马西平.PDF

中国环境科学 2018,38(1) ：193~201 China Environmental Science 电化学耦合膜工艺去除饮用水中卡马西平 孙继成,吴志超,王志伟,郑君健,王巧英* ( 同济大学环境科学与工程学院,污染控制与资源化研究国家重点实验 室,上 200092) 摘要：研究了外加电压、初始浓度对电化学耦合膜工艺去除饮用水中卡马西平(CBZ)效果的影响.结果表明,CBZ 初始浓度为 100µg/L 的条 件下,随着电压的升高, 电化学耦合膜工艺对 CBZ 的去除率逐渐增加,在外加电压为 2V , 电化学耦合膜工艺对 CBZ 的去除率达到 88.0%;外 加电压为 2.0V 的条件下,CBZ 初始浓度为 50~500µg/L 时, 电化学耦合膜对CBZ 的去除率均达到85%以上.而与粉末活性炭/微滤膜(PAC/MF) 工艺的比较可知, 电化学耦合膜工艺的去除效果更为稳定,运行成本也更低.考察了水中的离子强度和腐殖酸对电化学耦合膜工艺去除 CBZ 效果的影响.结果表明, 由于对系统中·OH 的竞争作用,离子强度的增大及腐殖酸浓度的提高将抑制 CBZ 去除. 关键词： 电化学耦合膜；粉末活性炭/微滤膜工艺；饮用水；卡马西平；腐殖酸 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2018)01-0193-09 The electrochemical coupled membrane process for the removal of CBZ in drinking water. SUN Ji-cheng, WU * Zhi-chao, WANG Zhi-wei, ZHENG Jun-jian, WANG Qiao-ying (State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China). China Environmental Science, 2018,38(1)：193~201 Abstract ：The removal of carbamazepine (CBZ) in drinking water by electrochemical coupled membrane process was investigated. The effects of voltage, initial CBZ concentration, ionic strength, and humic acid on the removal efficiency of CBZ were systemically investigated. The removal efficiency of CBZ gradually increased with the increase of applied voltage, and the optimal removal efficiency of CBZ was obtained with 2V applied voltage. When the initial CBZ concentration were in the range of 50 ~ 500µg/L, the removal efficiencies of CBZ by electrochemical coupled membrane process were above 85% by applying 2V voltage. However, the removal of CBZ could be inhibited by the increase of ionic strength and humic acid concentration due to the competitive effect o