超声场中电沉积二元纳米复合镀层的试验研究-机械设计及理论专业论文.docxVIP

河南科技大学硕士学位论文 河南科技大学硕士学位论文 PAGE PAGE IV III III 第四，对比研究了纯 Ni 镀层、一元复合镀层和二元复合镀层的显微硬度、 高温抗氧化性能和摩擦磨损性能。超声场中电沉积制备的 Ni-Y2O3-ZrO2 复合镀 层具有高的显微硬度、良好的高温抗氧化性能和摩擦磨损性能。这表明在两种纳 米颗粒和超声波的共同作用下，复合镀层获得了优良的综合性能。 第五，分析了影响二元纳米复合镀层性能的因素及其作用机理。在镀液中合 理配比的两种纳米颗粒可以促进彼此的共沉积；而超声波又可以促使这些纳米颗 粒在镀层中均匀分布，从而细化复合镀层的晶粒，改善其性能。 本论文通过研究，获得了超声场中制备抗高温和耐磨性能良好的 Ni-Y2O3- ZrO2 二元纳米复合镀层的复合电沉积工艺。本研究对开发具有优良性能的复合 镀层具有一定的参考价值。 关 键 词：直流电沉积，超声波，纳米颗粒，纳米复合镀层，微观结构，性能 论文类型：应用基础研究 摘 要 Subject: Experimental Investigation on Binary Nanocomposite Coatings by Electrodeposition in an Ultrasonic Field Specialty: Mechanical Design and Theory Name: Shen Chen Supervisor: Associate Professor Xue Yu-jun ABSTRACT Nanocomposite coatings, obtained by using composite electrodeposition technology, exhibited high wear resistance, temperature oxidation resistance, corrosion resistance, catalytic properties and so on. The properties of nanocomposite coatings mianly depended on the nature, type and distribution of nanoparticles as well as the process condition of the electrodeposition. Usually, nanocomposite coatings are prepared by adding one kind of nanoparticles into electrolyte using common method. Few researches on nanocomposite containing two kinds of nanopaticles were carried out. Ultrasonic could restrain the agglomeration of nanoparticles, refine grains of coatings and then favor the enhancement in properties of nanocomposite coatings. Thus, composite coatings with better properties are expected to be prepared by adding two kinds of nanoparticles into the electrolyte, combined with the strengthening effect of ultrasonic in electrodeposition process. In this dissertation, the fundamental research of binary nanocomposite coatings prepared by electrodeposition under ultrasonic condition was developed by adding rare earth Y2O3 and ceramics ZrO2 nanoparitcals into the electrolyte. Effects of the process parameters on the nanoparticle content in the composite coatings were investigated. The surface mo