多核及多孔配位聚合物的合成、结构及性质研究-无机化学专业论文.docxVIP

汕头大学硕士学位论文 汕头大学硕士学位论文 II II 配位聚合物超分子同分异构体系的构筑和在无前驱体、无硫族元素多桥连支撑条件下的多 核铜簇的构筑。深入研究了配位聚合物超分子同分异构体系的组装策略和合成方法，其中， 配体与金属离子配比的改变和溶剂的选择为我们得到了三个超分子同分异构体。 第 3 章在多孔配位聚合物的合成指导原则下，大胆提出假设：能够形成平面二维网络 结构的组装基元，在合适的模板剂作用下可得到一维纳米管，正如碳纳米管那样。这个想 法得到了实验的证实：通过过渡金属离子 Cu(Ⅱ)和三氮唑以及其它辅助配体自组装后可以 得到具有单壁纳米管状结构的配位聚合物。 第 4 章系统的研究了苯基咪唑系列(2,4,5—三苯基咪唑和 4，5—二苯基咪唑)桥连配体 及其与其它二齿螯合配体的竞争反应。阴离子和溶剂分子在配合物结构的形成过程中起到 了至关重要的作用。同时，对分子间弱作用：氢键（包括传统氢键和多中心的杂受体氢键） 和π—π堆积作了重点分析，对其如何影响结构作了深入探讨。苯基咪唑系列桥连配体与某 些二齿螯合配体的竞争反应也做了相应的研究。 通过实验的调查研究，我们认为配体本身的结构、配位水和中心金属离子的构型是影 响配合物中弱相互作用的重要因素。配体与配体之间的作用，例如：范得华力、静电作用、 氢键、芳环的堆积和疏水作用是构筑超分子体系的重要的分子间相互作用。 关键词：纳米组装、超分子异构体、多核、多孔配位聚合物、纳米管状结构 III III Abstract Supermolecular chemistry is one of the most popular and fastest growing areas of chemistry and it seems set to remain that way for the foreseeable future. supermolecular chemistry has been defined as “ chemistry beyond the molecule”. It based on all kinds of intermolecular weak interaction and research molecular aggregates. This is new landmark of chemistry development, while molecular recognitions、sites recognitions and molecular self-assembly are key issue of the research. We generally consider self-assembly is the process on the certain condition of building units spontaneous form well-order structure. It is important means that create new substance and produce new functions. In july of 2005 , it brought forward 25 important scientific issues in 21 century which remain to be solved in the 125-year Anniversary Special. The unique question of chemistry is : how far we can impel self-assembly of chemistry go? On the aspect of reflecting materially scientific significance in self-assembly of molecular. Molecular recognitions based on all kinds of intermolecular weak interaction are the formation foundation of supermolecular compound constructed by the general chemical compound. For the coordination chemistry, weak interactions usually behave as either intraligand or interligand interaction in the metal complexes. So i