掺杂磷酸铁锂正极材料的合成及改性研究物理化学专业论文.docxVIP

PAGE PAGE VI Abstract The cathode material is one of the key factors to determine the performances of lithium-ion batteries, and it accounts for about 40% of the entire cost of the battery. Therefore, it was very important to develop the high-performance cathode materials for the large-scale industrial application of lithium-ion battery. LiFePO4 has been considered as one of the most promising cathode materials for Li-ion batteries due to its low cost, good security and excellent cycle stability. However the electronic conductivity and Li+ diffusion rate of LiFePO4 were low, which limited the practical application of LiFePO4. In this paper, the olivine LiFePO4 was prepared by high temperature solid phase method using ferrous oxalate as the iron source, lithium carbonate as the lithium source and sugar as the carbon source. The impacts of the calcination temperature, holding time, milling media and carbon-coated amount on the structure, morphology and electrochemical performances of LiFePO4 materials were investigated. The results showed that when ethanol/water (the volume ratio was 4:1) was used as the milling media, and the amount of carbon-coated was 4 wt%, the materials synthesized at 700℃ for 15 h showed the best electrochemical performance. In order to improve the electrochemical performance of LiFePO4/C, Zn3(PO4)2 was coated on the surface of LiFePO4/C. The results showed that the discharge specific capacities of the materials were increases first and then decreases with the augmentation of the amount of Zn3(PO4)2. When the amount of the Zn3(PO4)2 coating was 1 wt.%, the initial discharge specific capacity of the material was 158 mAh g-1 at 0.1 C. The Ni2+ and Mn2+ doping were also studied in this paper. The LiNiyFe1-yPO4/C and LiMnyFe1-yPO4/C were synthesized by high temperature solid phase method using nickel acetate as the nickel source and manganese acetate as the manganese source. The structure, morphology and electrochemical performance of the LiNiyFe