噻呋酰胺的光解和水解特性研究.PDF

农药学学报 2016, 18(4): 540-544 Chinese Journal of Pesticide Science • 研究简报 • DOI: 10.16801/j.issn.1008-7303.2016.0077 噻呋酰胺的光解和水解特性研究 亓育杰, 杨 昱, 郑张瑜, 施海燕, 王鸣华* (南京农业大学 植物保护学院，南京 210095) 摘 要：为了明确噻呋酰胺的环境行为规律，采用室内模拟试验方法，研究了噻呋酰胺在不同 条件下的光解和水解特性。结果表明：紫外灯照射下，噻呋酰胺在碱性条件下光解速率大于中 性和酸性条件下的；不同溶剂中，噻呋酰胺的光降解速率依次为正己烷 ＞ 乙腈 ＞ 甲醇 ＞ 乙 酸乙酯 ＞ 超纯水；三价铁离子、二价铁离子以及腐殖酸均能抑制噻呋酰胺的光降解。中性条 件下，噻呋酰胺水解速率最快，同时，噻呋酰胺的水解受温度影响，温度越高，水解速率越 快，平均温度效应系数 1.39~2.23 ；表面活性剂十六烷基三甲基溴化铵 (CTAB) 和十二烷基磺酸 钠 (SDS) 均可抑制噻呋酰胺在水中的降解。 关键词: 噻呋酰胺；光解；水解 中图分类号：S482.2；TQ450.2 文献标志码：A 文章编号：1008-7303(2016)04-0540-05 Study on the photolysis and hydrolysis properties of thifluzamide * QI Yujie , YANG Yu , ZHENG Zhangyu , SHI Haiyan , WANG Minghua (College of Plant Protection, Nanjing Agricultural University, Nanjing 210095, China) Abstract: The photolytic and hydrolytic properties of thifluzamide under different conditions were investigated by using the indoor simulation test method. The results showed that the photolytic rate of thifluzamide, was much faster in alkaline solutions compared to that in the neutral and acidic solutions under ultraviolet irradiation. The photolytic rate of thifluzamide in different solvents followed the sequence: n-hexane acetonitrile methanol ethylacetate ultrapure water. The ferr