添加剂对电镀锌稀土转化膜成膜作用机理的研究-IngentaConnect.PDF

48 / 2 11 5 Effects of Additives on Formation Interaction Mechanism of Rare Earth Conversion Coating of Zinc Plating 1 2 , ( 1 , 65 93; 2 , 65 93) 1 2 ZHANG Jianghong , ZHANG Yingjie ( 1 Faculty of Science, Kunming U niversity of Science and Technology, Kunming 65 93, China; 2 Faculty of M etallurgical and Energy Engineering, Kunming U niversity of Science and Technology, Kunming 65 93, China) : , , , : H O , , H O , 2 2 2 2 pH , ; , , : ; ; ; : T G 174. 44 : A : 1 14381( 2 11) 5 48 5 Abstract: It w as of great significance to the efficient formation of rare earth conversion coating w ith high corrosion resistance by using chemical immersion method through the addition of oxidant and promoter of coatingformation for the preparation of rare earth conversion coating on the surface of zinc plating. T he results show that through the electrochemistry test, morphology analysis and dy namics data calculation, reductive reaction at microcathode is speeded up by the addition of oxidant 2 2 H O into the treatment solution, and promoting the increase of pH w ithin the microcathode region, w hich is favorable to the formation of conversion coating w ith high content of Ce. T he addition of