《保龄球形氧化锌的制备和表征及其光学性质》-毕业学术论文设计.docVIP

保龄球形氧化锌的制备和表征及其光学性质 学院、专业 物理与电子信息学院 材料物理专业 研 究 方 向 光电子材料 学 生 姓 名 学 号 指导教师姓名 指导教师职称 副 教 授 2011年 04月 28日 保龄球形氧化锌的制备和表征及其光学性质 摘要 本实验以锌粉为原料，氧化铟为催化剂，加入碳粉，用化学气相法（CVD）烧制出了保龄球状的氧化锌结构。并通过X射线衍射(XRD)，扫描电镜（SEM），光致发光(PL)等测试手段对保龄球形氧化锌的形貌和光学性能进行了研究。 X射线衍射实验结果分析知样品的三个特征峰分别为ZnO（100）、ZnO（002）、ZnO（101），经对图谱线强度的分析知样品的结晶度为86.32%。结晶完整且结晶晶粒较大。并知ZnO在［0001］方向上生长优越性突出。 扫描电镜实验结果可以清楚地看出ZnO保龄球形形貌。其晶粒尺寸约为2μm～4μm。同时对样品不同区域的大量观察总结出保龄球形结构ZnO的生长过程。 PL光谱结果表明，所得保龄球形氧化锌样品在450～600nm间有一绿色发光带。约504.5nm处有一绿光发射峰.。通过分析知在504.5nm处绿光发射峰应属于导带底到氧反位缺陷能级的跃迁所导致的发光。 关键词 氧化锌；化学气相法；制光致发光；生长机制 Bowling-shaped ZnO nano structures and optical properties of preparation, characterization Zhou Zhenting School of Physics and Electronic Information, Huaibei Normal University, 235000 Abstract We fabricate bowling-shaped ZnO nano structures with zinc and carbon powder as reactive sources and oxidation indium as catalyst, in the vapor chemical reactive stove. The scanning electron microscopy (SEM), X-ray diffraction (XRD), and photoluminescence spectrum are used to determined the morphology, crystal structres and optical properties of bowling-shaped ZnO . Three characteristic diffraction peaks (100), (002), and (101), belonging to ZnO wurtzite phase, are indentified from the X-ray diffraction patterns. The crystallization ratio of 86.32% could be obtained, according to the diffractive peak strength. The crystal orientation [0001] is the preferential growth ones. We can see ZnO bowling shape morphology clearly from scanning electron microscopy experimental results. Its grain size is about 2μm ~ 4μm. We observe different areas of a sample and conclude the growth mechanics of bowling-shaped ZnO. The PL spectra show that our ZnO samples have a green emission band between 450 ~600nm with the peak at 504.5nm. We think the green light peak at 504.5nm should come from the transition of defect levels of oxygen vac