毕业论文-聚醚醚酮膜光催化分离膜的制备与表征论文.docVIP

PAGE XXV 学校代码： 学 号： University 毕业论文 BACHELOR DISSERTATION 论文题目： 聚醚醚酮膜光催化分离膜的制备与表征 学位类别： 工学学士 学科专业： 化学工程与工艺 作者姓名： 导师姓名： 完成时间： 2013.6.3 PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT IV PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT III 聚醚醚酮膜光催化分离膜制备与表征 摘 要 本文研究了以聚醚醚酮为膜材料制得经过磺化改性的聚醚醚酮膜和在膜上负载二氧化钛后制得光催化分离膜，并对膜进行硝酸浸泡前后的性能表征和测试光催化分离膜的光催化活性。主要对不同磺化时间的聚醚醚酮膜进行性能表征，主要包括拉伸强度、离子交换容量、含水率、磺化度等，还通过光催化降解亚甲基蓝测试光催化分离膜的光催化活性。 拉伸强度随磺化度增大而减小；膜的离子交换容量随磺化时间变长而变大；膜的含水率受其磺化时间影响很小，可以忽略；硝酸浸泡后对膜的拉伸强度、离子交换容量、含水率等性能影响较小，说明该膜具有耐酸性。比较有无添加二氧化钛的亚甲基蓝溶液的在紫外灯下的降解率，验证了二氧化钛粉具有光催化活性；而后添加二氧化钛和致孔剂后制得光催化分离膜在紫外灯下比白炽灯照射下的降解率高。有望具有光催化和膜分离的多功能性和膜物性的改变，并且解决光催化剂的回收和减缓膜污染等难题。 关键词：光催化分离膜；聚醚醚酮；磺化；酸处理；二氧化钛；性能表征 Preparation and Characterization of PEEK membrane and Photocatalytic membrane Abstract This paper studies peek membrane prepared by sulfonation modification and photocatalysis separating film using titanium dioxide supported on the membrane which membrane material is peek. Then testing performance characterization of membrane after nitric acid dipping and photocatalytic activity of photocatalytic membrane. The membranes’ fundamental properties with different sulfonation times, such as tensile strength, ion-exchange capacity, water content moisture content, degree of sulfonation was explored. We also test photocatalytic activity of photocatalytic membrane by measuring degradation of methylene blue. The results show that with increasing of the reaction time, the membrane tensile strength reduced, but the change of the ion exchange capacity and water content moisture content becomes small. After the nitric acid dipping, tensile strength, ion exchange capacity, water extent have no changes, indicating that the film has acid resistance. It verifies the titanium dioxi