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O]NOF
I之ESEARCH0FTHEPOIYREACTI
ACIDICHETEROPOIjY10NIC
ROSINOVER
CATALYSTS
LIQUID
ABSTRACT
kindsofacidic ionic were and
Nineteen synthesizedby
heteropolyliquid designed
the of cationsand basedonthe
adjustmentproportionorganic heteropolyanions
ofionic structureof
liquids.The optimized
designability
characterizedFT-IRand
by
Sm0.33[TEAPS]2PWl2040,A1066[MIMPS]PWl2040)were
tomeasuretheacid
1H.NMR.Potentiometrictitration wasintroduced
bybutylamine
characterof and Was
catalyststhermogravimetry-differentialscanningcalorimetryapplied
of
todetectthethermal ofthe effects
stabilitycatalysts.Thetemperature,reactiontime,
solvent of onrosin reactionhavebeen
type,thedosagecatalyst polymerization
overtheabove reused ofthese
more,thepropertiescatalysts
investigated catalysts.what’S
werealsostudied.
1.FT-IR、1H.NMRindicatedthatthefree in acid
spectrums hydrogenphosphotungstic
MIMPS+toformthe ionic
was TEAPS+or
by h
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