Al与Al-Mn合金层在一种AlCl3型离子液体中的电沉积制备及其腐蚀行为.PDF

第27 卷 第6 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol.27 No.6 2015 年11 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Nov. 2015 Al 与Al-Mn 合金层在一种AlCl 型离子液体中 3 的电沉积制备及其腐蚀行为 陈 彬 盛鹏飞 王建明 张鉴清 曹楚南 浙江大学化学系 杭州 310027 摘要：在AlCl -EMIC (氯化1- 甲基-3-乙基咪唑) 或AlCl -MnCl -EMIC 离子液体中采用电沉积的方法在20#钢表 3 3 2 面制备了Al 和Al-Mn 合金镀层。利用能量色散X 射线(EDX)、扫描电镜(SEM)、X 射线衍射(XRD) 及极化曲 线等方法对所制备镀层的组成、形貌、结构和腐蚀性能进行了表征与测试。所制备的Al-Mn 合金镀层是致密 的，与基体结合良好。电化学实验结果表明，Al 和Al-Mn 合金镀层的腐蚀速率低于20#钢基体；Mn 含量为 20.26% 的Al-Mn 合金镀层显示了最好的耐蚀性。 关键词：电沉积 Al Al-Mn 合金 离子液体 腐蚀 中图分类号：TQ 153.2 文献标识码：A 文章编号：1002-6495(2015)06-0571-05 Electrodeposition of Al and Al-Mn Alloy Coatings on Carbon Steel with Ionic Liquids and Their Corrosion Behavior CHEN Bin, SHENG Pengfei, WANG Jianming, ZHANG Jianqing, CAO Chunan Department of Chemistry, Zhejiang University, Hangzhou 310027, China Abstract: Al and Al-Mn alloy coatings were electrodeposited on 20# steel substrate with ionic liq- uids of AlCl -EMIC (1-ethyl-3-methylimidazolium chloride) or AlCl -MnCl -EMIC. The composi- 3 3 2 tion, morphology, microstructure and corrosion behavior of the coatings were characterized by SEM with EDS, XRD analysis and polarization curves. The electrodeposited Al-Mn alloy coatings are dense, with good adhesion on 20# steel substrate. The results of electrochemical tests showed that the as- fabricated Al and Al- Mn alloy coatings have lower corrosion rates than the bare