增强TMA改性膨润土吸附性能的方法研究-Core.PDFVIP

2014,34(3) 638~643 China Environmental Science TMA 1 1 1,2* 1 1 , , , , (1., 411105 2. , 510640) + + : Li , Li (TMA)(20%60% CEC);180 12h Li+ , . TMA ,, HOCs .TMA 20% CEC , 2 2 2 (236m /g vs 131m /g),. X703 A 2014 1 1 Methods of increasing the adsorption capacity of TMA-bentonites. CHENG Xing-rong , ZHAO Jun-bo , ZHU 1,2* 1 1 Run-liang , XU Yin , GE Fei (1.Department of Environmental Science, Xiangtan University, Xiangtan 411105, China 2.Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China). China Environmental Science, 2014,34(3)638~643 Abstract A new method that can increase the exposure of siloxane surface was developed in this work. First the inorganic cations on bentonite were exchanged with Li+, and then a part of the Li+ were further exchanged with tetramethylammonium cation (TMA), i.e., 20% or 60% of the bentonites cation exchange capacity. After that the samples were heated under 180 for 10h to make sure that most of the Li+ were transferred to bentonite sheets. By this way, the layer charge of bentonites can be effectively reduced while the layers of bentonite can be preserved by preexchanged TMA. The resulting organic bentonite showed larger specific surface areas and better adsorption capacity than those synthesized using traditional method (i.e., first reducing the charge density and then exchanging TMA). For example, in the case of organic bentonite with 20% CEC TMA, the one synthesized using new method has almost twice the specific surface areas as the one synthesized using traditional method (236 vs 131m2/g), and the adso