《CZ／TMTD并用促进剂对NR的改性实验》》-毕业论文.doc

摘要 本研究项目以CZ对NR改性配方为基础配方，目的是通过CZ/TMTD（N-环己基-2-苯并噻唑次磺酰胺/二硫化四甲基秋兰姆）对NR改性实验，来研究CZ/TMTD多元促进剂并用的硫化体系对改善NR拉伸性能、硬度和回弹等性能的影响，从而确定CZ/TMTD多元促进剂并用的硫化体系对NR物理机械性能的作用意义。 本次实验主要分为以下三步：一是天然橡胶生胶性能测试；二是CZ对NR的改性实验；三是CZ/TMTD并用促进剂对NR的改性实验。 实验结果表明，加入促进剂可提高胶料的硬度、回弹性及拉伸强度；在相同配方中，延长硫化时间可提高胶料的硬度、回弹性及拉伸强度；并用促进剂CZ/TMTD比促进剂CZ对胶料硬度、回弹性及拉伸强度的影响更大；在配方中使用CZ/TMTD不仅能减少硫磺用量，还能提高胶料的硬度、回弹性及拉伸强度。仅从硬度、回弹性及拉伸强度三个方面考虑，并用促进剂CZ/TMTD比促进剂CZ对NR物理机械性能影响更大。 关键词：天然橡胶；并用促进剂；拉伸性能；硬度；回弹性 Abstract The precise foundation formula of this research project is CZ modified natural rubber. CZ/TMTD(N-cyclohexyl-2-benzothiazolyl sulfonamide/tetramethyl thiuram disulfide) on the NR modified experiments to study the accelerator and multiple curing systems of CZ/TMTD used to improve the tensile properties, hardness and elasticity and other properties of the natutal rubber. It’s purpose is studying on the role of blend accelerator CZ/TMTD on the property of NR. This experiment is mainly divided into the following three steps: first is raw natural rubber performance testing; the second is CZ on NR modification experiments; the third is CZ/TMTD on NR modification experiments. The results show that adding rubber accelerator can improve the hardness, elasticity and tensile strength; in the same formula, the extension of rubber vulcanization time can enhance the hardness, elasticity and tensile strength; using accelerator CZ/TMTD has greater impact than using accelerator CZ on rubber hardness, elasticity and tensile strength; using in the formulation CZ/TMTD can not only reduce the sulfur content, but also improve the hardness of rubber, elasticity and tensile strength. Only from the hardness, elasticity and tensile strength of the three areas to consider, using accelerator CZ/TMTD has greater impact than using accelerator CZ on the physical and mechanical properties of NR. Keywords: Natural Rubber; Blend Accelerator; Tensile Properties; Hardness; Elasticity 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc263789883 第一章 绪论 PAGEREF _Toc2637898