《铝合金微弧氧化陶瓷膜制备工艺及优化》-毕业论文.docVIP

西南石油大学化学化工院 摘 要 在很多特殊的工业领域，为满足某些特殊的性能需求，需要用到铝及其合金，但铝及其合金的表面硬度低、耐腐蚀性与耐磨性差、抗热震性差制约了铝合金的应用。通过表面处理工艺进行处理，可以提高铝合金的综合性能，微弧氧化工艺是在阳极氧化工艺基础上发展起来的新兴表面处理技术，微弧氧化膜层具有硬度高，绝缘性与耐腐蚀性和耐磨性好，高抗热震性，氧化膜与基体结合力强等优点，极大地提高了铝合金的应用范围。 本文用微弧氧化技术对铝合金表面进行强化处理,利用正交试验设计优化试验方案, 按4因素（Na2SiO3浓度、KOH浓度、H3BO3 浓度、微弧氧化电压）3水平得到正交表,合理安排微弧氧化试验, 达到优化微弧氧化工艺条件的目的：并用极差法评价各因素对陶瓷膜硬度和厚度影响的主次顺序和可能最优水平。结果表明,铝合金微弧氧化陶瓷膜的硬度和厚度受各因素水平的影响显著, 其中Na2SiO3浓度对陶瓷膜硬度和厚度两指标的影响最大；在最优工艺条件下(Na2SiO3浓度6g/L、H3BO3浓度1.5g/L、KOH浓度0.5g/L、微弧氧化电压360V) ,陶瓷膜致密层总厚度约 200 μm。 关键词:铝合金；微弧氧化；正交试验设计；表面处理；陶瓷氧化膜。 Abstract In many industries, to meet special performance requirements, it must be used in aluminum and its alloys, aluminum and its alloys, but lower surface hardness, corrsion resistance and poor wear resistance, thermal shock resistance is poor, restricted application of aluminum alloy. Can be processed by surface treatment to improve the comprehensive peforrmance of aluminum alloy. Oxidation in the anodic oxidation process developed on the basis of the newsurface treatment technology, micro-arc oxidation film has high hardness, corrsion resistance and insulation resistance and good wear resistance, high thermal shock resistance,oxide film and the substrate combined with strong advantages, greatly improved the application of aluminun alloy. Applying the technology of micro-arc oxidation to strengthen handling the surface of aluminum alloy, optimal experiments were designed by or thogonal experimental and the or thogonal table was gained according to fuor elements (concentration of Na2 SiO3, concentration of KOH, concentration of H3 BO3, micro-arc oxidation voltage) and three levels, carry out the micro-arc oxidation experiments appropriately, for the aim to obtain condi tions in which micro-arc oxidation technics can be optimized, using the i ntegral balanceable method to estimate the possibly optimal level and evaluate the primary and secondary order of effect to the hardness and thickness of ceramic coating caused by different elements. The