特征提取的改性麦糟吸附三价砷离子模型.PDFVIP

第42卷 第9期 北 京 工 业 大 学 学 报 Vol.42 No.9 2016年 9月 JOURNAL OF BEIJING UNIVERSITY OFTECHNOLOGY Sept. 2016 特征提取的改性麦糟吸附三价砷离子模型 梁礼明,吴摇 健,陈召阳,朱摇 莎 (江西理工大学电气工程及自动化学院,江西 赣州摇 341000) 摘摇 要:由于改性麦糟吸附三价砷离子As(芋)的过程复杂,引入特征提取的方法将能够快速发现实验中各因素对 吸附率的影响,揭示改性麦糟吸附As(芋)的最适条件和最佳效果. 应用线性降维方法主成分分析和非线性降维方 法流形学习提取官能基团和吸附活性质之间的关系. 最后,利用支持向量回归模型和偏最小二乘法模型建立构效 关系模型,探寻得出最佳吸附条件为:改性剂浓度1mg/ L,改性剂溶液pH为7,改性时间为12h,反应温度为20益, 吸附时间为2h,改性麦糟用量为0郾3mg,吸附率能达到96郾19%. 关键词:特征提取;改性麦糟;主成分分析;流形学习;支持向量机回归 中图分类号:TP391郾9;TQ015郾9 文献标志码:A 文章编号:0254-0037(2016)09-1294-07 doi:10.11936/ bjutxb2015090045 Model for Modified Spent Grains Adsorption As(III) Ions With Feature Extraction LIANG Liming,WUJian,CHEN Zhaoyang,ZHU Sha (School of Electrical Engineering and Automation,Jiangxi University of Science and Technology,Ganzhou341000,Jiangxi,China) Abstract:Exploringthe optimum conditionfor modified spent grains爷adsorption of As(III)iscomplex, this paper introduces a feature extraction method to help find the influence on adsorption rate for each factor during the experiment, to discover the optimum condition for modified spent grains to adsorb As(III). To extract the relationship between functional group and adsorption properties, both linear principal component analysis method and nonlinear manifold learning methodwere adoptedfor dimension reduction. Finally,the quantitative structure activity relationship with support vector regress and partial least squares was established to find out the optimum condition for adsorption. Results show that the modifier concentration is 1 mg/ L,the PH value of solution is 7, modification time is 12 h,reaction temperature is20 益,adsorption time is2h,dose of