不同侧链氧氮苯并环己烷奈米复材合成与特性之研究-国立高雄科技大学.doc

中文摘要 聚氧氮苯并環己烷(Polybenzoxazine)由於在硬化過程中具有良好尺寸安定性、低吸濕性、耐化學性等優點，因此在近年來被廣泛的研究。然而Benzoxazine本身交聯密度低，所以耐熱性及機械性質仍顯不足。因此，利用Benzoxazine良好的分子設計彈性，或是利用添加補強材形成複合材料，以提高其熱穩定性及機械性質。 本研究主要目的在製備不同側鏈氧氮苯并環己烷，並混摻多面體矽氧烷寡聚物(POSS)後形成奈米複合材料。首先利用無溶劑法選用不同的雙酚類與苯胺、三聚甲醛先行合成不同側鏈的Benzoxazine: 6,6-bis(3-phenyl-3,4dihydro-2H-1,3-benzoxazinyl) isopropane (Bz-A), 6,6-bis(3-phenyl-3,4dihydro-2H-1,3-benzoxazinyl) methylene (Bz-F), 6,6-bis(3-phenyl-3,4dihydro-2H-1,3-benzoxazinyl) thylbenzene(Bz-ap)，利用FTIR、1H-NMR進行結構鑑定，並利用微分掃描熱卡計(DSC)探討其熱硬化行為，經硬化後的Benzoxazine利用DMA、TGA探討其物性。實驗結果顯示，Benzoxazine在硬化過程中具有自催化的效果。熱機械性質與熱穩定性方面，Bz-F由於分子結構立體障礙小，具有較高的交聯密度，因此有較佳的機械性質與耐熱性質。 將不同含量的POSS分別加入Benzoxazine系統中形成奈米複合材料，探討奈米複合材料的熱硬化行為及其硬化物之物性。由結果顯示，添加POSS後會降低Benzoxazine硬化時的自催化效果。熱機械性質與熱穩定性方面，POSS添加量在5wt%時具有最佳的機械性質與耐熱性。 英文摘要 Polybenzoxazines have evinced significant interest as a class of high performance polymer. These novel materials gain attention because of low volumetric shrinkage upon curing, minimal moisture absorption, excellent resistance to chemicals. However, the low crosslinking densities of benzoxazine resins leaded to insufficient in mechanical properties and thermal stability. Therefore, for improve mechanical properties and thermal stability, the molecular design flexibility and added reinforcements would be employ. The goal of this research is focused on the synthesis of different side chain benzoxazines and hybrid with polyhedral oligomeric silsesquioxane(POSS) to preparation for nanocomposites. 6,6-Bis(3-phenyl-3,4dihydro-2H-1,3-benzoxazinyl) isopropane (Bz-A), 6,6-bis(3-phenyl-3,4dihydro-2H-1,3-benzoxazinyl) methylene (Bz-F) and 6,6-bis(3-phenyl-3,4dihydro-2H-1,3-benzoxazinyl) ethylbenzene (Bz-ap) can be use the bisphenols which contain different pendant group with aniline and paraformaldehyde through solventless method to synthesis. The structure of synthesized Benzoxazines will be confirmed by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), and th