磁性钛酸钠的可控制备及其性能研究-无机化学专业论文.docx

I I 摘 要 采用水热法设计制备钛酸钠纳米材料，通过 XRD、SEM、TEM、UV-VIS/DRS 等 仪器进行分析、表征材料的结构和特性。利用不同温度下制备的钛酸钠对水中 Sr2+进 行吸附，研究吸附动力学和热力学模型，确定 pH、温度等影响因素及最佳吸附条件。 将已有的磁铁- Fe3O4 的人工合成改性方法拓展到磁性 Na2Ti3O7 材料的合成体系，将 Fe3O4 可控锚定在 Na2Ti3O7 表面。再通过 pH 值、初始物的浓度配比、压力、温度、加 热方式和时间等条件来调控磁性钛酸钠的形貌及其复合结构。磁性钛酸钠对 Sr2+具有 较高的吸附能力和速率，并可实现简易、快捷回收再利用。以罗丹明 B、甲基橙为光 催化降解对象，研究了磁性钛酸复合材料的光催化性能及其增强机理，为新型污染物 光催化降解材料的研究提供依据。 关键词：钛酸钠；磁性 Fe3O4 ；Sr2+吸附；磁性钛酸；光催化 II II ABSTRACT Hydrothermal method is used to design the preparation of sodium titanate nano materials, with XRD, SEM, TEM and UV-VIS/DRS instrument analysis and characterization of the structure and properties. The adsorption of Sr2+ in water condition based on different temperature, making study on Adsorption Kinetics and thermodynamics model, ensure that the effect elements of pH, temperature and other factors and the best adsorption condition. The artificial synthesis of existing magnet, modified Fe3O4 method is extended to synthetic system of magnetic Na2Ti3O7 Material, Fe3O4 controllable anchored on the surface of the Na2Ti3O7. Going through the pH value, the initial concentration ratio, the pressure, the temperature, the heating approaches to control the magnetic sodium titanate and its composite structure. The magnetic sodium titanate to Sr2+ has a very high adsorption capacity and rate, and can realize simple, quick and recycling. By the photocatalytic degradation of Rhodamin B and Benzoic Acid(Methyl Orange) as the object of study, the photocatalytic properties of magnetic composite titanate and its strengthening mechanism, provide the basis for studying new material in the photocatalytic degradation of pollutants. Key words: sodium titanate; Magnetic Fe3O4; Sr2+ adsorption; Magnetic titanate; photocatalytic III III 目 录 HYPERLINK \l _bookmark0 摘 要 I HYPERLINK \l _bookmark1 ABSTRACT II HYPERLINK \l _bookmark2 目 录 III HYPERLINK \l _bookmark3 第一章 绪 论 1 HYPERLINK \l _bookmark4 1.1 引 言 1 HYPERLINK \l _bookmark5 1.2 钛酸钠 1 HYPERLINK \l _bookmark6 1.2.1 钛酸钠纳