超支化阳离子聚丙烯酰胺的合成及其应用性能研究-纺织化学与染整工程专业论文.docxVIP

II II 中文摘要 超支化阳离子聚丙烯酰胺的合成及应用性能研究 较稳定，对直接红 81 和直接蓝 78 染色织物的色光有一定的影响，并用 SEM 扫描 电子显微镜分析了整理前后织物的表面形貌。 关键词: 超支化聚酯；阳离子；聚丙烯酰胺；抗静电；固色 作 者：陈 焜 指导老师：周向东 教授 PAGE PAGE IV Synthesis and application of cationic hyperbranched polyacrylamide Abstract Synthesis and application of cationic hyperbranched polyacrylamide Abstract Hyperbranched polymers contain many advantages such as a large number of end-groups, high reactivity and good rheological behavior. It is easy to graft a new group by chemical modification in order to obtain a novel application. In recent years, many hyperbranched polyesters which contain double bond have been reported by domestic and overseas researchers. This kind of hyperbranched polyester can cross link with itself and can also polymeric with other monomers. For these advantages, in this dissertation, modified hyperbranched polyester was prepared and a novel cationic polymer was synthesized. The structure and properties of the polymers were studied. The application on antistatic agent and fixing agent were investigated. The details were as follows: The modified hyperbranched polyester (WHBP) was synthesized by acrylic acid (AA) and glycidyl trimethylammonium chloride (GTA). After that, a cationic hyperbranched polyacrylamide P(WHBP-AM-AGE) was synthesized by WHBP, acrylamide (AM) and allyl glycidyl ether (AGE). The structures and properties were studied by FTIR, 1HNMR and TG-DTG. The optimal synthetic conditions were as follows: m(AM) : m(AGE) : m(WHBP) = 1:1:2, initiator was 1.5%, the temperature was 80oC and the reaction time was 5 h. The synthetic P(WHBP-AM-AGE) was used as antistatic agent on nylon fabric. After the fabric was treated at the temperature of 170oC for 120 s under the concentration of 25 g/L, and the pH=5 ~ 7, the static voltage of treated fabric was 0.13 kV and the half-time was 0.09 s. After 10 launderings, the static voltage of treated fabric was 0.48 kV and the half-time was 0.56 s. Moreover, the shape and el