气相色谱法监测氧化钙催化制备生物柴油的反应进度Monitoring.PDF

2007 年第65 卷 化 学 学 报 Vol. 65, 2007 第18 期, 2025～2028 ACTA CHIMICA SINICA No. 18, 2025～2028 ·研究论文· 气相色谱法监测氧化钙催化制备生物柴油的反应进度 刘晓华a 吴宗斌b 张 萍*,a 汤志勇a 朱华平a 段世杰b 毛宗强*,b (a 中国地质大学材料科学与化学工程学院 武汉 430074) (b 清华大学核能与新能源技术研究院 北京 100084) 摘要 建立了一种通过检测氧化钙催化制备生物柴油过程中产生的甘油来监测反应进度的方法. 在反应样品中加入草 酸、硫酸溶液, 除掉由催化剂引入的钙离子, 释放与氧化钙结合的甘油, 利用气相色谱方法检测甘油的含量. 讨论了实 验中加入草酸、硫酸的目的及对结果的影响. 实验结果表明, 此法可用于氧化钙催化制备生物柴油过程中反应进度监 测的研究. 关键词 生物柴油; 检测; 甘油; 气相色谱; 转化率 Monitoring Reactive Degree of Biodiesel Catalyzed by Calcium Oxide via Gas Chromatography LIU, Xiao-Huaa WU, Zong-Binb ZHANG, Ping*,a TANG, Zhi-Yonga ZHU, Hua-Pinga DUAN, Shi-Jieb MAO, Zong-Qiang*,b a ( Faculty of Material Science and Chemical Engineering, China University of Geosciences, Wuhan 430074) (b Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084) Abstract In this work, a method of quantitatively analyzing glycerol to monitor the reactive degree of bio- diesel catalyzed by calcium oxide was established. The calcium ions originated from catalysts were removed and the glycerol combined with calcium oxide was released by adding oxalic acid and sulfuric acid to the products. The amount of glycerol was measured by the gas chromatography. The aims and the influences of oxalic acid, sulfuric acid in the system were discussed. At the same time, the method was used in studying the kinetics of the transesterification. Keywords biodiesel; monitor; glycerol; gas chromatography; con